4.6 Article

MOF-Supported Copper Complex-Catalyzed Synthesis of Unsymmetrical 1,3-Diynes Without External Additives

期刊

CHEMCATCHEM
卷 14, 期 13, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202200235

关键词

heterogeneous catalysis; metal-organic frameworks; Glaser heterocoupling reaction; unsymmetrical 1,3-diynes

资金

  1. National Natural Science Foundation of China [21872060, 21902054, 22072049]
  2. Innovation and Talent Recruitment Base of New Energy Chemistry and Device
  3. HUST Academic Frontier Youth Team [2019QYTD06]

向作者/读者索取更多资源

Cu complexes supported on metal-organic frameworks (MOFs) demonstrated high catalytic efficiency in Glaser heterocoupling reactions. The newly designed MIL-101-NH-TMEDA.CuClx showed the highest catalytic activity and selectivity compared to other reference catalysts, without the need for external ligands.
Cu complexes supported on metal-organic frameworks (MOFs) with N-1,N-1,N-2,N-2-tetramethylethylenediamine (TMEDA) were prepared via post-synthetic modification, and proved to be highly efficient for Glaser heterocoupling reactions. Compared with some referential catalysts, which were prepared by using a series of copper salts and Cu-0 nanoparticles as the copper sources, the newly designed MIL-101-NH-TMEDA.CuClx exhibited highest catalytic activity and selectivity in the model Glaser heterocoupling reaction. Much lower activity was observed with the homogeneous counterpart, TMEDA.CuCl4. Intriguingly, the Glaser heterocoupling reactions over MIL-101-NH-TMEDA.CuClx catalyst can be conducted without adding external ligands, base, or acid, which are always necessary in the previously reported systems. The dense catalytic active sites in the MOF channels and the adsorption properties of the MOF were conjectured to be partially responsible for the observed high catalytic activity, which may allow the formation of a unique internal environment in the three-dimensional porous framework that significantly boosted progress of the reactions. The X-ray photoelectron spectroscopy (XPS) results showed also that the catalytically active copper species changed from Cu-II to Cu-I after catalytic use.

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