期刊
CHEMCATCHEM
卷 14, 期 15, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202200144
关键词
aluminium; hydrides; main group metal catalysis; hydrogenation; imines
资金
- European Research Council (ERC) [CoG 683150]
- Projekt DEAL
This article introduces a catalytic hydrogenation of amines using a bimetallic Li/Al dihydride catalyst. The research demonstrates that the preparation of this catalyst is relatively simple.
Hydrogenations have been dominated by transition metal catalysis, while the use of more abundant and inexpensive main group metal catalysts has remained a great challenge. Here, a bimetallic Li/Al dihydride was successfully applied to catalytic hydrogenations of imines. The catalyst [((Dipp)BIAN)Al(mu-H)(2)Li(OEt2)(2)] was easily prepared from the 2e-reduced BIAN derivative and LiAlH4.
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