4.7 Article

Strengthening the thermal Negative Poisson's ratio structures by SiC chemical vapor infiltration

期刊

CERAMICS INTERNATIONAL
卷 48, 期 16, 页码 22782-22788

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.04.094

关键词

3D printing; Chemical vapor infiltration; Thermal expansion; Ceramic matrix composites

资金

  1. National Key R&D Program of China [2021YFB3701500]
  2. National Natural Science Foundation of China [52072306, 51772246]
  3. National Science and Technology Major Project [2017-VI-0007-0077]
  4. Science Foundation of the National Key Laboratory of Science and Technology on Advanced Composites in Special Environments [6142905192509]
  5. Fundamental Research Funds for the Central University [3102019PJ008, 3102018jcc002]

向作者/读者索取更多资源

A unique negative Poisson's ratio structure was designed, and its reliability and thermal stability were improved through heat-induced torsion and SiC material enhancement technology. The structure performed well in terms of thermal expansion control and load-bearing capacity.
Negative Poisson's ratio structures exhibit adjustable thermal expansion behavior as the thermal stress can be dispersed or offset by torsion, bending, and tension of the struts. However, the structural stability under cyclic thermal stress significantly determines the long-term durability. Strengthening the Negative Poisson's ratio structure can ensure high thermal and mechanical reliability. The work designed a heat-induced torsional Negative Poisson's ratio structures and fabricated it by 3D printing. For efficient strengthening, the preforms were further densified by chemical vapor infiltration (CVI) of SiC to enhance the reliability. Pores and gaps in the preforms were homogeneously covered and filled by the SiC, enhancing the surface finish and mechanical performance. The heat induced torsion of the structures dispersed the heat flow in one single direction, reducing the thermal stress concentration. The independent thermal expansion change of the structural unit can offset or consume the heat dissipation stress, and further improve the reliability and thermal stability through the densification process. As a result, the 120 degrees. twisted structure exhibited an average coefficient of thermal expansion (CTE) of 6. 12 x 10(-6)/K from room temperature (RT) to 500 degrees C, and the instantaneous CTE reached the minimum value of 4.01 x 10(-6)/K at 125 degrees C. Meanwhile, the load-bearing capacity strengthened significantly, exhibiting the optimized strength of 11.31 MPa and Young's Modulus of 36.44 GPa, revealing a significant improvement than those of preforms, promising for high load-bearing and low expansion application of structure-function integrated low expansion material.

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