期刊
CERAMICS INTERNATIONAL
卷 48, 期 18, 页码 26575-26584出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.05.353
关键词
Core-shell structure; Microwave absorbing property; Porous material; Multiple reflections
资金
- National Natural Science Foundation of China [62004144, 61904127]
- Guangdong Basic and Applied Basic Reuter Foundation [2021A1515010651]
- National Dam Safety Research Center [CX2020B07]
- Fundamental Research Funds for the Central Universities [213201006, 213134005]
In this paper, the authors successfully synthesized WO3@WC materials with core-shell porous structure and investigated their microstructure, morphology, phase analysis, and electromagnetic property. The experimental results demonstrated that the core-shell porous structure can significantly improve the microwave absorption property of the materials and exhibit good microwave absorbing effects.
Special microstructure can significantly improve the microwave absorption property of rare materials. In this paper, porous WC powders were successfully synthesized by spray granulation method. Then, WO3@WC materials with core-shell porous structure can be prepared after 410 degrees C heating treatment at different time to form the outer WO 3 oxidation layer. In addition, the microstructure, morphology, phase analysis and electromagnetic property were fully studied by investigating the WC-based materials in different structures. For WO3@WC coreshell porous materials, when the coating thickness was 2.1 mm, the maximum reflection loss can reach -19.4 dB at 12.6 GHz, which shows quite good microwave absorbing effects. The core-shell porous structure enhances the original microwave absorption performance due to the multiple reflection reflections and polarizations.
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