期刊
CATALYSIS LETTERS
卷 153, 期 3, 页码 720-731出版社
SPRINGER
DOI: 10.1007/s10562-022-04009-z
关键词
Furfural; Furfuryl alcohol; Quercetin-zirconium; Meerwein-Ponndorf-Verley reduction (MPV)
The utilization of renewable raw materials to synthesize functional solid catalytic materials is an attractive topic. In this study, an amorphous Quercetin-Zr catalyst was synthesized using quercetin and ZrCl4, which exhibited excellent catalytic activity and high yield of furfuryl alcohol.
The utilization of renewable raw materials to synthesize functional solid catalytic materials is a very attractive topic. Herein, an amorphous Quercetin-Zr catalyst was synthesized by using quercetin and ZrCl4 as raw materials. Quercetin-Zr had excellent catalytic transfer hydrogenation activity and can efficiently convert furfural to furfuryl alcohol and obtain a 97.9% yield of furfuryl alcohol after 1.5 h at 120 degrees C. Systematic characterization established the existence of a large amount of Lewis acid-base couple sites (Zr4+-O2--) in quercetin-Zr, which maximized furfuryl alcohol production through acid-base synergistic catalysis. [GRAPHICS] .
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