4.5 Article

Shedding Light on the Lewis Acid Catalysis in Organic Transformations Using a Zn-MOF Microflower and Its ZnO Nanorod

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Effect of calcination temperature on the morphology and catalytic properties of ZnO nanostructures fabricated from a chiral precursor for photodegradation of both cationic and anionic dyes

Shradha Gandhi et al.

Summary: Diverse ZnO nanostructures with interesting optical and photocatalytic properties were successfully synthesized through calcination of a chiral MOF precursor at different temperatures. These nanostructures showed good efficiency in degrading organic pollutants and exhibited recyclability and photostability.

NEW JOURNAL OF CHEMISTRY (2022)

Review Chemistry, Multidisciplinary

Toward Active-Site Tailoring in Heterogeneous Catalysis by Atomically Precise Metal Nanoclusters with Crystallographic Structures

Rongchao Jin et al.

Summary: Researchers have successfully synthesized atomically precise metal nanoclusters with well-defined structures, opening up new opportunities for catalysis research. These atomically precise nanoclusters combine the characteristics of homogeneous catalysts and enzymes, holding significant potential for practical applications.

CHEMICAL REVIEWS (2021)

Article Chemistry, Inorganic & Nuclear

Nanochannel {InZn}-Organic Framework with a High Catalytic Performance on CO2 Chemical Fixation and Deacetalization-Knoevenagel Condensation

Hongtai Chen et al.

Summary: A robust hybrid material of {(Me2NH2)[InZn(TDP)(OH2)]center dot 4DMF center dot 4H(2)O}(n) (NUC-42) was developed, featuring interlaced hierarchical nanochannels shaped by six rows of undocumented [InZn(CO2)(6)(OH2)] clusters, representing the first 5p-3d nanochannel-based heterometallic metal-organic framework. The catalytic performance of activated NUC-42a was evaluated for CO2 cycloaddition with styrene oxide and deacetalization-Knoevenagel condensation reactions, showing high efficiency under mild conditions.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Physical

1D Zn(II) Coordination Polymers as Effective Heterogeneous Catalysts in Microwave-Assisted Single-Pot Deacetalization-Knoevenagel Tandem Reactions in Solvent-Free Conditions

Anup Paul et al.

Summary: Two new 1D CPs have been prepared and characterized, showing potential as heterogeneous catalysts for tandem reactions under environmentally friendly conditions.

CATALYSTS (2021)

Article Chemistry, Inorganic & Nuclear

6s-3d {Ba3Zn4}-Organic Framework as an Effective Heterogeneous Catalyst for Chemical Fixation of CO2 and Knoevenagel Condensation Reaction

Hongtai Chen et al.

Summary: The exquisite combination of Ba2+ and Zn2+ with H6TDP under solvothermal self-assembly conditions generates a highly stable 2D-based organic framework NUC-27, which displays a unique Z-shaped heterometallic cluster structure for efficient catalysis on the chemical transformation of epoxides and CO2.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

被撤回的出版物: Cu(II)-Containing Metal-Organic Framework with 1D Hexagonal Channels for Cyanosilylation Reaction and Anticancer Activity on Osteosarcoma Cells (Retracted article. See vol. 7, pg. 9087, 2022)

Jian Luo et al.

Summary: A novel metal-organic framework was synthesized and explored as a catalyst for cyanosilylation. The compound was evaluated for its inhibitory function against osteosarcoma cell survival rate, as well as for its effects on cell apoptosis levels and ROS accumulation.

ACS OMEGA (2021)

Article Chemistry, Inorganic & Nuclear

Three Resorcin[4]arene-Based Two-Dimensional Zn(II) Supramolecular Isomers Synthesized via a Structure-Directing Strategy for Knoevenagel Condensation

Fei-Fei Wang et al.

Summary: In the presence of three structure-directing agents, a series of imidazole-functionalized resorcin[4]arene-based coordination polymers were successfully assembled under solvothermal conditions, exhibiting remarkable catalytic performance and utilizing a small organic acid as a structure-directing agent for the first time.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Highly Stable Polyoxovanadate-Based Zn-MOF with Dual Active Sites as a Solvent-free Catalyst for C-C Bond Formation

Hongrui Tian et al.

Summary: The zinc-organic framework V-Zn-MOF combines rich Lewis acid and base sites, efficiently catalyzing Knoevenagel condensation and cyanosilylation of aromatic aldehydes. The synergetic effect of open zinc sites as Lewis acid and {V2O6}(n)(2n-) polyanion as Lewis base contributes to the selective catalytic activity. The connection mode of {V2O5}-O-Zn enhances efficiency by reducing the molecular size distance between substrates.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Nanoscience & Nanotechnology

Indium-Organic Framework with soc Topology as a Versatile Catalyst for Highly Efficient One-Pot Strecker Synthesis of α-aminonitriles

Gaurav Verma et al.

Summary: The In-based MOF In-pbpta with soc topology showed high surface area and pore volume, making it a promising catalyst for the one-pot multicomponent Strecker reaction. The strong interactions between substrates and the In-oxo cluster in the MOF lead to efficient catalytic conversion within a short period of time, indicating its potential as a new class of efficient heterogeneous catalyst.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Multidisciplinary

Functional Porphyrinic Metal-Organic Framework as a New Class of Heterogeneous Halogen-Bond-Donor Catalyst

Weijie Zhang et al.

Summary: This study reported a novel metal-metalloporphyrin framework catalyst utilizing halogen bonding as a donor for catalyzing Diels-Alder reactions, showing high efficiency and uniqueness in facilitating organic transformations. Through experimental and computational studies, the substrate molecules were demonstrated to diffuse through the pores of the framework, establishing a host-guest system via the C-Br...pi interaction, which plays a key role in boosting catalytic efficiency. Furthermore, the unique capability of the metal-metalloporphyrin framework highlights new opportunities in using artificial non-covalent binding pockets as highly tunable and selective catalytic materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Inorganic & Nuclear

Metal-organic framework composites as green/sustainable catalysts

Kuan-Guan Liu et al.

Summary: MOFs have been widely used as catalysts due to their brilliant characteristics, and the composite method is an important approach to optimize their performance. Green MOF composites show great potential in environmental-friendly catalysis applications.

COORDINATION CHEMISTRY REVIEWS (2021)

Article Chemistry, Inorganic & Nuclear

Cuboctahedral [In36(μ-OH)24(NO3)8(Imtb)24]MOF with Atypical Pyramidal Nitrate Ion in SBU: Lewis Acid-Base Assisted Catalysis and Nanomolar Sensing of Picric Acid

Sharad Kumar Sachan et al.

Summary: The multifunctional MOF with a unique metal cluster core exhibits significant catalytic activity and higher TOF in chemical reactions, while also being utilized for detecting explosive material TNP.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Ligand-Directed Conformational Control over Porphyrinic Zirconium Metal-Organic Frameworks for Size-Selective Catalysis

Liting Yang et al.

Summary: Zirconium-based metal-organic frameworks (Zr-MOFs) have garnered significant interest due to their stability, flexible structures, and unique functions. This study introduces a new Zr-MOF (PCN-625) with a csq topological net, featuring vertical porphyrin rings and one-dimensional channels with different diameters. PCN-625 demonstrates potential as a heterogeneous catalyst for selective cycloaddition reactions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Review Chemistry, Physical

Incorporation of homogeneous organometallic catalysts into metal-organic frameworks for advanced heterogenization: a review

Sandeep Kumar et al.

Summary: Catalysis is a promising technique in various fields, with heterogeneous catalysts like MOFs being used to convert homogeneous catalysts for improved reusability and selectivity. MOFs, as organic-inorganic hybrid materials, have been developed as candidates for various applications by incorporating homogeneous catalysts into a heterogeneous framework. This new approach combines the properties of both compounds to generate hybrid heterogeneous catalysts with the benefits of both the organometallic compound and the MOFs constituents.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

Review Chemistry, Inorganic & Nuclear

A review of the recent progress on heterogeneous catalysts for Knoevenagel condensation

Jimmy Nelson Appaturi et al.

Summary: This review discusses the most pertinent heterogeneous catalytic systems in the Knoevenagel reaction, such as zeolites, mesoporous silica, ionic liquids, metal oxides, and graphitic carbon nitride-based catalysts. The focus is not only on the catalyst but also on providing an overall idea and guide for the preparation of new catalysts with outstanding properties by considering chemical and engineering aspects such as reaction conditions and mechanisms.

DALTON TRANSACTIONS (2021)

Article Chemistry, Multidisciplinary

A robust heterogeneous Co-MOF catalyst in azide-alkyne cycloaddition and Friedel-Crafts reactions as well as hydrosilylation of alkynes

Tai-Xue Wu et al.

Summary: A stable Co(ii)-MOF has been successfully synthesized and can serve as a heterogeneous catalyst for various organic reactions with excellent catalytic performance and recyclability.

NEW JOURNAL OF CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives

Anastasiya Bavykina et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Multidisciplinary

Highly Stable Zr(IV)-Based Metal-Organic Frameworks with Chiral Phosphoric Acids for Catalytic Asymmetric Tandem Reactions

Wei Gong et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective

Vlad Pascanu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Strongly Lewis Acidic Metal-Organic Frameworks for Continuous Flow Catalysis

Pengfei Ji et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Robust Corrole-Based Metal-Organic Frameworks with Rare 9-Connected Zr/Hf-Oxo Clusters

Yanming Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Green & Sustainable Science & Technology

One-pot three-component synthesis of α-amino nitriles using ZnO as a heterogeneous, reusable, and eco-friendly catalyst

Balwinder Kaur et al.

JOURNAL OF CLEANER PRODUCTION (2019)

Article Multidisciplinary Sciences

Double-slit photoelectron interference in strong-field ionization of the neon dimer

Maksim Kunitski et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Inorganic & Nuclear

Robust heterometallic MOF catalysts for the cyanosilylation of aldehydes

Jia-Jia Du et al.

INORGANIC CHEMISTRY FRONTIERS (2018)

Article Chemistry, Multidisciplinary

Controlled Exchange of Achiral Linkers with Chiral Linkers in Zr-Based UiO-68 Metal-Organic Framework

Chunxia Tan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Chemistry, Multidisciplinary

Metal organic frameworks as precursors for the manufacture of advanced catalytic materials

Lide Oar-Arteta et al.

MATERIALS CHEMISTRY FRONTIERS (2017)

Article Chemistry, Multidisciplinary

A Mesoporous Indium Metal-Organic Framework: Remarkable Advances in Catalytic Activity for Strecker Reaction of Ketones

Daniel Reinares-Fisac et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

Base-free Knoevenagel condensation catalyzed by copper metal surfaces

E. M. Schneider et al.

CHEMICAL COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Carbon Dioxide Capture in Metal-Organic Frameworks

Kenji Sumida et al.

CHEMICAL REVIEWS (2012)

Review Chemistry, Multidisciplinary

Chiral-at-metal complexes and their catalytic applications in organic synthesis

Eike B. Bauer

CHEMICAL SOCIETY REVIEWS (2012)

Review Chemistry, Multidisciplinary

Optical chemosensors and reagents to detect explosives

Yolanda Salinas et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Chemistry, Inorganic & Nuclear

Two ligand-functionalized Pb(II) metal-organic frameworks: structures and catalytic performances

Xiao-Ming Lin et al.

DALTON TRANSACTIONS (2012)

Article Chemistry, Multidisciplinary

Orthogonal Enantioselectivity Approaches Using Homogeneous and Heterogeneous Catalyst Systems: Friedel-Crafts Alkylation of Indole

Hun Young Kim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Review Chemistry, Multidisciplinary

Metal-organic framework materials as catalysts

JeongYong Lee et al.

CHEMICAL SOCIETY REVIEWS (2009)

Review Chemistry, Multidisciplinary

Selective gas adsorption and separation in metal-organic frameworks

Jian-Rong Li et al.

CHEMICAL SOCIETY REVIEWS (2009)

Article Chemistry, Multidisciplinary

Cationic and Anionic Surface Binding Sites on Nanocrystalline Zinc Oxide: Surface Influence on Photoluminescence and Photocatalysis

D. Scott Bohle et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

Nanocrystalline ZnO for Knoevenagel condensation and reduction of the carbon,carbon double bond in conjugated alkenes

Mona Hosseini-Sarvari et al.

HELVETICA CHIMICA ACTA (2008)

Article Chemistry, Multidisciplinary

Three-dimensional porous coordination polymer functionalized with amide groups based on tridentate ligand: Selective sorption and catalysis

Shinpei Hasegawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

Review Chemistry, Multidisciplinary

Metal carboxylates with open architectures

CNR Rao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

Article Public, Environmental & Occupational Health

Exposure to nitroaromatic explosives and health effects during disposal of military waste

S Letzel et al.

OCCUPATIONAL AND ENVIRONMENTAL MEDICINE (2003)

Article Chemistry, Multidisciplinary

Growth of arrayed nanorods and nanowires of ZnO from aqueous solutions

L Vayssieres

ADVANCED MATERIALS (2003)

Article Chemistry, Inorganic & Nuclear

Homochiral Zn and Cd coordination polymers containing amino acid-tetrazole ligands

ZR Qu et al.

INORGANIC CHEMISTRY (2003)