期刊
CARBON
卷 193, 期 -, 页码 51-67出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2022.03.008
关键词
Graphene nanoflakes; Oxygen-containing organic compounds; Radiofrequency thermal plasma; Continuous synthesis; Catalyst-free synthesis
资金
- Polish National Agency for Aca-demic Exchange (NAWA) within the Bekker Program [PPN/BEK/2020/1/00013]
- Budapest, Hungary
- Hungarian National Research Development and Innovation Office
- European Union
- State of Hungary - European Regional Development Fund
The aim of this study was to investigate the potential of oxygen-containing organic compounds as precursors for graphene flakes. Plasma processing was used to treat nine different compounds, and the impact of various operating parameters on product formation rate and yield was thoroughly examined. The morphology, graphitization, thermal stability, and chemical composition of the obtained materials were analyzed. It was found that five compounds were suitable for continuous synthesis of graphene flakes, while one compound resulted in a mixture of graphene flakes and byproducts.
The aim of this work was to test the oxygen-containing organic compounds as prospective precursors of graphene flakes in a radiofrequency thermal plasma jet. The research covered the plasma processing of nine compounds, including alcohols, carboxylic acids, etc. Herein, the influence of the operating parameters, namely pressure, applied power, precursor feeding rate, and addition of hydrogen, on the efficiency of the product formation rate and yield was thoroughly studied. The morphology of the obtained materials was investigated by electron microscopy. The graphitization was evaluated via Raman spectroscopy. The thermal stability of products was studied utilizing thermogravimetry. Finally, the chemical composition was determined using X-ray photoelectron spectroscopy. Five compounds (ethanol, butyric acid, propionic acid, acetic anhydride, acetaldehyde) were found to be suitable precursors for continuous synthesis of graphene flakes, while ethyl acetate gave the mixture of graphene flakes and quasi-spherical byproduct. The plasma processing of methanol, formic acid, and acetic acid did not form any solid product.
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