期刊
BIOSENSORS & BIOELECTRONICS
卷 200, 期 -, 页码 -出版社
ELSEVIER ADVANCED TECHNOLOGY
DOI: 10.1016/j.bios.2021.113917
关键词
MXene; AgBr nanocrystal; Electrochemiluminescence; Near-infrared; Enrofloxacin
类别
资金
- National Natural Science Foundation of China [21904014, 21904015, 22178031, 51874050]
- Natural Science Foundation of Jiangsu Province [BK20190928, BK20211062]
- China Postdoctoral Science Foundation [2020M671366]
- Postdoctoral Science Foundation funded project of Jiangsu Province [2020Z266]
- Jiangsu Association of Science and Technology Young Talent Support Project [2020-07]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [21KJA610001]
- Changzhou Association of Science and Technology Young Talent Support Project, Science Foun-dation of Changzhou [CZ20200038]
- Jiangsu Province Key Labo-ratory of Materials Surface Science and Technology [KFBM20210001]
This study presents the preparation of well-dispersed AgBr nanocrystals decorated Ti3C2 MXene nanocomposites (Ti3C2-AgBrNCs) using a simple wet chemical technique, which exhibited highly efficient near-infrared electrochemiluminescence (ECL) emission. The ECL emission wavelength of Ti3C2-AgBrNCs was found to be tunable by varying the Ti3C2 content, and Ti3C2-AgBrNCs showed higher ECL intensity and more stable ECL signal compared to pure AgBr NCs. A direct-type near-infrared ECL aptasensor was constructed using Ti3C2-AgBrNCs as the ECL platform and enrofloxacin (ENR) as the model analyte, demonstrating high sensitivity, a wide linear range, and a low detection limit.
Toxic-free and easily accessible electrochemiluminescence (ECL) emitter/luminophore with near-infrared (NIR) emission is highly anticipated for ECL biosensor evolution. In this study, well-dispersed AgBr nanocrystals (NCs) decorated Ti3C2 MXene nanocomposites (Ti3C2-AgBrNCs) were prepared using a simple wet chemical technique and demonstrated highly efficient NIR ECL emission. For the first time, Ti3C2-AgBrNCs displayed wavelength tunable ECL emission with varied Ti3C2 contents. Interestingly, further experimental data revealed that the ECL emission wavelength of Ti3C2-AgBrNCs red-shifted from 550 to 665 nm as Ti3C2 content increased, which can be attributed to the surface-defect effect generated by the oxygen-containing functional groups in Ti3C2 MXene. In particular, the ECL emission at 665 nm of Ti3C2 -AgBrNCs nanocomposites not only revealed a 3.5 times increased ECL intensity but also a more stable ECL signal compared to pure AgBr NCs. As a proof of concept, a direct-type NIR ECL aptasensor with signal-on strategy was constructed with the Ti3C2 -AgBrNCs nanocomposites as an ECL platform and enrofloxacin (ENR) as a model analyte. The NIR ECL aptasensor exhibited high sensitivity, a wide linear range from 1.0 x 10(-12) mol/L to 1.0 x 10(-6) mol/L and a low detection limit (5.97 x 10(-13) mol/L). This research offered a viable alternative way for producing toxic-free and efficient near-infrared ECL luminophores in bioanalysis and wavelength-tuning light-emitting devices.
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