☆ 4.8 Article

2D metal carbides and nitrides (MXenes) for sensors and biosensors

BIOSENSORS & BIOELECTRONICS (2022)

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Summary: In this study, titanium carbide Ti3C2Tx (MXene) was synthesized at high temperature and nanocrystalline iron oxide (alpha-Fe2O3) was obtained through a single solid-phase method. The Ti3C2Tx-Fe2O3 nanocomposite exhibited high electro-catalytic activity for H2O2 reduction, showing a linear response range from 10 nM to 1 mu M H2O2. This composite modified electrode successfully detected H2O2 in food and urine samples, suggesting its potential application in non-enzymatic H2O2 sensors for medical diagnosis, food safety, and environmental monitoring.

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Summary: MXene, a novel material consisting of two-dimensional transition metal carbides/nitride, has superior physical and chemical properties suitable for environmental remediation of toxic compounds. With its highly hydrophilic surface, ion exchange property, and robust surface functional groups, MXene is widely employed in separation techniques like photocatalysis, adsorption, and membrane separation for the removal of toxic pollutants. The review paper comprehensively discusses the structural patterns, preparation, properties, and application of MXene, emphasizing its significance in addressing priority environmental pollutants and challenges in synthesis and use for decontamination purposes.

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Summary: MXenes are a new class of 2D materials with high conductivity and hydrophilicity, making them versatile for various analytical chemistry applications such as electrochemical and optical sensing. Their exceptional surface chemistry, high surface area, and ease of functionalization contribute to their potential as excellent materials for analytical extractions. Limitations, challenges, and future opportunities for MXenes are briefly discussed.

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Keming Wan et al.

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Tianzi Xia et al.

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Integrating Highly Efficient Recognition and Signal Transition of g-C3N4 Embellished Ti3C2 MXene Hybrid Nanosheets for Electrogenerated Chemiluminescence Analysis of Protein Kinase Activity

Yan Sun et al.

ANALYTICAL CHEMISTRY (2020)

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Article Biophysics

Gold nanoparticle/MXene for multiple and sensitive detection of oncomiRs based on synergetic signal amplification

Mohsen Mohammadniaei et al.

BIOSENSORS & BIOELECTRONICS (2020)

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Article Materials Science, Ceramics

Synthesis of two-dimensional carbide Mo2CTx MXene by hydrothermal etching with fluorides and its thermal stability

Yitong Guo et al.

CERAMICS INTERNATIONAL (2020)

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Article Materials Science, Multidisciplinary

Electrochemical detection of amyloid-β protein by delaminated titanium carbide MXene/multi-walled carbon nanotubes composite with molecularly imprinted polymer

Nermin Ozcan et al.

MATERIALS TODAY COMMUNICATIONS (2020)

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Article Biophysics

In-situ engineered MXene-TiO2/BiVO4 hybrid as an efficient photoelectrochemical platform for sensitive detection of soluble CD44 proteins

Razium Ali Soomro et al.

BIOSENSORS & BIOELECTRONICS (2020)

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Article Engineering, Environmental

Thermal reduction of sulfur-containing MAX phase for MXene production

Jun Mei et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Electrochemistry

Nb-based MXenes for efficient electrochemical sensing of small biomolecules in the anodic potential

P. Abdul Rasheed et al.

ELECTROCHEMISTRY COMMUNICATIONS (2020)

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Article Chemistry, Analytical

Toward agricultural ammonia volatilization monitoring: A flexible polyaniline/Ti3C2Tx hybrid sensitive films based gas sensor

Xian Li et al.

SENSORS AND ACTUATORS B-CHEMICAL (2020)

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Article Chemistry, Multidisciplinary

An Electrodeposited MXene-Ti3C2TxNanosheets Functionalized by Task-Specific Ionic Liquid for Simultaneous and Multiplexed Detection of Bladder Cancer Biomarkers

Md. Sharifuzzaman et al.

SMALL (2020)

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Review Chemistry, Multidisciplinary

Recent Developments of Carbon Dots in Biosensing: A Review

Chunyu Ji et al.

ACS SENSORS (2020)

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Article Chemistry, Multidisciplinary

Exploring the Influence of Critical Parameters for the Effective Synthesis of High-Quality 2D MXene

Sana Munir et al.

ACS OMEGA (2020)

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Article Engineering, Environmental

Taking MXenes from the lab to commercial products

Christopher E. Shuck et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Analytical

An electrochemical biosensor based on AuNPs/Ti3C2 MXene three-dimensional nanocomposite for microRNA-155 detection by exonuclease III-aided cascade target recycling

Xiao Yang et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2020)

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Article Chemistry, Analytical

A dual-potential electrochemiluminescence sensor for ratiometric detection of carcinoembryonic antigen based on single luminophor

Lei Shang et al.

SENSORS AND ACTUATORS B-CHEMICAL (2020)

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Article Chemistry, Multidisciplinary

Universal in Situ Crafted MOx-MXene Heterostructures as Heavy and Multifunctional Hosts for 3D-Printed Li-S Batteries

Chaohui Wei et al.

ACS NANO (2020)

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Article Nanoscience & Nanotechnology

Annealed Ti3C2Tz MXene Films for Oxidation-Resistant Functional Coatings

Xiaofei Zhao et al.

ACS APPLIED NANO MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Dual-readout proximity hybridization-regulated and photothermally amplified protein analysis based on MXene nanosheets

Huizhu Ren et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

Fluoride-Free 2D Niobium Carbide MXenes as Stable andBiocompatible Nanoplatforms for Electrochemical Biosensors with Ultrahigh Sensitivity

Menglin Song et al.

ADVANCED SCIENCE (2020)

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Article Nanoscience & Nanotechnology

A Signal Amplification Strategy of CuPtRh CNB-Embedded Ammoniated Ti3C2 MXene for Detecting Cardiac Troponin I by a Sandwich-Type Electrochemical Immunosensor

Hui Dong et al.

ACS APPLIED BIO MATERIALS (2020)

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Article Chemistry, Physical

Oxidation-resistant titanium carbide MXene films

Yonghee Lee et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Multidisciplinary

Carbon nanomaterials for salivary-based biosensors: a review

H. Ehtesabi

MATERIALS TODAY CHEMISTRY (2020)

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Article Materials Science, Multidisciplinary

Latest advances in MXene biosensors

Bingzhe Xu et al.

JOURNAL OF PHYSICS-MATERIALS (2020)

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Article Materials Science, Biomaterials

Ti3C2Tx MXene-derived TiO2/C-QDs as oxidase mimics for the efficient diagnosis of glutathione in human serum

Zhaoyong Jin et al.

JOURNAL OF MATERIALS CHEMISTRY B (2020)

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Article Nanoscience & Nanotechnology

Laser-Scribed Graphene Electrodes Derived from Lignin for Biochemical Sensing

Yongjiu Lei et al.

ACS APPLIED NANO MATERIALS (2020)

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Review Chemistry, Multidisciplinary

Recent development and prospects of surface modification and biomedical applications of MXenes

Hongye Huang et al.

NANOSCALE (2020)

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Article Engineering, Environmental

Metal - organic frameworks-derived MnO2/Mn3O4 microcuboids with hierarchically ordered nanosheets and Ti3C2 MXene/Au NPs composites for electrochemical pesticide detection

Dandan Song et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize Nanolaminated MAX Phases and MXenes

Mian Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Analytical

Ultrathin Ti3C2 nanosheets based off-on fluorescent nanoprobe for rapid and sensitive detection of HPV infection

Xiuying Peng et al.

SENSORS AND ACTUATORS B-CHEMICAL (2019)

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Article Chemistry, Multidisciplinary

A MXene-Based Wearable Biosensor System for High-Performance In Vitro Perspiration Analysis

Yongjiu Lei et al.

SMALL (2019)

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Article Chemistry, Physical

Modulating the Schottky barriers in MoS2/MXenes heterostructures via surface functionalization and electric field

Qiong Peng et al.

APPLIED SURFACE SCIENCE (2019)

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Article Biophysics

A label-free electrochemical biosensor for highly sensitive detection of gliotoxin based on DNA nanostructure/MXene nanocomplexes

Hui Wang et al.

BIOSENSORS & BIOELECTRONICS (2019)

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Article Chemistry, Multidisciplinary

Nafion-stabilized two-dimensional transition metal carbide (Ti3C2TX MXene) as a high-performance electrochemical sensor for neurotransmitter

Faisal Shahzad et al.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2019)

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Article Engineering, Multidisciplinary

Fabrication on the annealed Ti3C2Tx MXene/Epoxy nanocomposites for electromagnetic interference shielding application

Lei Wang et al.

COMPOSITES PART B-ENGINEERING (2019)

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Article Biophysics

A 2D transition metal carbide MXene-based SPR biosensor for ultrasensitive carcinoembryonic antigen detection

Qiong Wu et al.

BIOSENSORS & BIOELECTRONICS (2019)

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Article Materials Science, Biomaterials

MXene-Ti3C2/CuS nanocomposites: Enhanced peroxidase-like activity and sensitive colorimetric cholesterol detection

Yapeng Li et al.

MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS (2019)

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Article Chemistry, Analytical

Strand displacement dual amplification miRNAs strategy with FRET between NaYF4:Yb,Tm/Er upconversion nanoparticles and Ti3C2 nanosheets

Feng Chen et al.

SENSORS AND ACTUATORS B-CHEMICAL (2019)

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Article Chemistry, Multidisciplinary

MXene-Enabled Electrochemical Microfluidic Biosensor: Applications toward Multicomponent Continuous Monitoring in Whole Blood

Jiang Liu et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Review Biophysics

Ti3C2 MXenes nanosheets catalyzed highly efficient electrogenerated chemiluminescence biosensor for the detection of exosomes

Huixin Zhang et al.

BIOSENSORS & BIOELECTRONICS (2019)

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Article Chemistry, Physical

Ti3C2Tx MXene and polyoxometalate nanohybrid embedded with polypyrrole: Ultra-sensitive platform for the detection of osteopontin

Sijie Zhou et al.

APPLIED SURFACE SCIENCE (2019)

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Article Chemistry, Inorganic & Nuclear

Hydrolysis of 2D Transition-Metal Carbides (MXenes) in Colloidal Solutions

Shuohan Huang et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Ti3C2 MXene quantum dot-encapsulated liposomes for photothermal immunoassays using a portable near-infrared imaging camera on a smartphone

Guoneng Cai et al.

NANOSCALE (2019)

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Article Nanoscience & Nanotechnology

Three-Dimensional Porous Ti3C2Tx MXene-Graphene Hybrid Films for Glucose Biosensing

Hui Gu et al.

ACS APPLIED NANO MATERIALS (2019)

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Review Electrochemistry

Review-Recent Exploration of Two-Dimensional MXenes for Gas Sensing: From a Theoretical to an Experimental View

Eunji Lee et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

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Article Nanoscience & Nanotechnology

Size-Dependent Physical and Electrochemical Properties of Two-Dimensional MXene Flakes

Kathleen Maleski et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Chemistry, Multidisciplinary

Metallic Ti3C2TX MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio

Seon Joon Kim et al.

ACS NANO (2018)

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Article Chemistry, Multidisciplinary

Surface Nanopore Engineering of 2D MXenes for Targeted and Synergistic Multitherapies of Hepatocellular Carcinoma

Zhenli Li et al.

ADVANCED MATERIALS (2018)

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Article Biophysics

2D transition metal carbide MXene as a robust biosensing platform for enzyme immobilization and ultrasensitive detection of phenol

Lingxia Wu et al.

BIOSENSORS & BIOELECTRONICS (2018)

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Article Engineering, Environmental

Silver nanoparticles modified two-dimensional transition metal carbides as nanocarriers to fabricate acetycholinesterase-based electrochemical biosensor

Yanjun Jiang et al.

CHEMICAL ENGINEERING JOURNAL (2018)

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Article Chemistry, Multidisciplinary

High-yield fabrication of Ti3C2Tx MXene quantum dots and their electrochemiluminescence behavior

Yunlong Qin et al.

NANOSCALE (2018)

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Article Chemistry, Multidisciplinary

Ratiometric photoluminescence sensing based on Ti3C2 MXene quantum dots as an intracellular pH sensor

Xu Chen et al.

NANOSCALE (2018)

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Article Chemistry, Analytical

Ultra-sensitive electrocatalytic detection of bromate in drinking water based on Nafion/Ti3C2Tx (MXene) modified glassy carbon electrode

P. Abdul Rasheed et al.

SENSORS AND ACTUATORS B-CHEMICAL (2018)

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Review Chemistry, Multidisciplinary

Recent Advances in Layered Ti3C2Tx MXene for Electrochemical Energy Storage

Dongbin Xiong et al.

SMALL (2018)

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Review Chemistry, Analytical

MXene: An emerging material for sensing and biosensing

Ankita Sinha et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2018)

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Article Materials Science, Multidisciplinary

High photoluminescence quantum yield of 18.7% by using nitrogen- doped Ti3C2 MXene quantum dots

Quan Xu et al.

JOURNAL OF MATERIALS CHEMISTRY C (2018)

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Article Biophysics

Biofunctionalized two-dimensional Ti3C2 MXenes for ultrasensitive detection of cancer biomarker

Saurabh Kumar et al.

BIOSENSORS & BIOELECTRONICS (2018)

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Article Chemistry, Multidisciplinary

Binder-free 2D titanium carbide (MXene)/carbon nanotube composites for high-performance lithium-ion capacitors

Peng Yu et al.

NANOSCALE (2018)

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Article Chemistry, Analytical

Few-layer Ti3C2Tx MXene: A promising surface plasmon resonance biosensing material to enhance the sensitivity

Leiming Wu et al.

SENSORS AND ACTUATORS B-CHEMICAL (2018)

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Review Chemistry, Analytical

Recent Advances in Electrochemiluminescence Analysis

Lingling Li et al.

ANALYTICAL CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Two-Dimensional Ultrathin MXene Ceramic Nanosheets for Photothermal Conversion

Han Lin et al.

NANO LETTERS (2017)

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Article Chemistry, Physical

Synthesis of two-dimensional Ti3C2Tx MXene using HCl plus LiF etchant: Enhanced exfoliation and delamination

Tian Zhang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2017)

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Article Polymer Science

Preparation and characterization of polymer-Ti3C2Tx (MXene) composite nanofibers produced via electrospinning

Elisa A. Mayerberger et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2017)

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Article Chemistry, Multidisciplinary

2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)

Patrick Urbankowski et al.

NANOSCALE (2017)

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Article Biotechnology & Applied Microbiology

Acetylcholinesterase/chitosan-transition metal carbides nanocomposites-based biosensor for the organophosphate pesticides detection

Liya Zhou et al.

BIOCHEMICAL ENGINEERING JOURNAL (2017)

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Article Nanoscience & Nanotechnology

Room Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene)

Eunji Lee et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Article Chemistry, Multidisciplinary

Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance

Chuanfang (John) Zhang et al.

ADVANCED MATERIALS (2017)

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Article Chemistry, Multidisciplinary

MXene Electrode for the Integration of WSe2 and MoS2 Field Effect Transistors

Jiao Xu et al.

ADVANCED FUNCTIONAL MATERIALS (2016)

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Article Chemistry, Multidisciplinary

Organic-Base-Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance

Jinnan Xuan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Physical

Theoretical Prediction of the Intrinsic Half-Metallicity in Surface-Oxygen-Passivated Cr2N MXene

Guo Wang

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

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Article Chemistry, Multidisciplinary

Schottky-Barrier-Free Contacts with Two-Dimensional Semiconductors by Surface-Engineered MXenes

Yuanyue Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Multidisciplinary

Efficient phosphate sequestration for water purification by unique sandwich-like MXene/magnetic iron oxide nanocomposites

Qingrui Zhang et al.

NANOSCALE (2016)

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Article Nanoscience & Nanotechnology

Vibrational and mechanical properties of single layer MXene structures: a first-principles investigation

Ugur Yorulmaz et al.

NANOTECHNOLOGY (2016)

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Article Multidisciplinary Sciences

Electromagnetic interference shielding with 2D transition metal carbides (MXenes)

Faisal Shahzad et al.

SCIENCE (2016)

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Article Chemistry, Analytical

MXenes: Reusable materials for NH3 sensor or capturer by controlling the charge injection

Bo Xiao et al.

SENSORS AND ACTUATORS B-CHEMICAL (2016)

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Article Chemistry, Multidisciplinary

Ti3C2Tx (MXene)-polyacrylamide nanocomposite films

Michael Naguib et al.

RSC ADVANCES (2016)

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Article Nanoscience & Nanotechnology

Optical properties of functionalized Ti3C2T2 (T=F, O, OH) MXene: First-principles calculations

G. R. Berdiyorov

AIP ADVANCES (2016)

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Article Chemistry, Physical

Computational studies on the structural, electronic and optical properties of graphene-like MXenes (M2CT2, M = Ti, Zr, Hf; T = O, F, OH) and their potential applications as visible-light driven photocatalysts

Haijun Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

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Article Materials Science, Multidisciplinary

High temperature spin-polarized semiconductivity with zero magnetization in two-dimensional Janus MXenes

Junjie He et al.

JOURNAL OF MATERIALS CHEMISTRY C (2016)

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Article Chemistry, Physical

2D titanium carbide and transition metal oxides hybrid electrodes for Li-ion storage

Meng-Qiang Zhao et al.

NANO ENERGY (2016)

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Article Electrochemistry

Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage

Chang E. Ren et al.

CHEMELECTROCHEM (2016)

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Article Nanoscience & Nanotechnology

Fabrication of Ti3C2Tx MXene Transparent Thin Films with Tunable Optoelectronic Properties

Kanit Hantanasirisakul et al.

ADVANCED ELECTRONIC MATERIALS (2016)

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Article Multidisciplinary Sciences

Novel amperometric glucose biosensor based on MXene nanocomposite

R. B. Rakhi et al.

SCIENTIFIC REPORTS (2016)

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Article Chemistry, Multidisciplinary

Dependence of elastic and optical properties on surface terminated groups in two-dimensional MXene monolayers: a first-principles study

Yuelei Bai et al.

RSC ADVANCES (2016)

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Article Nanoscience & Nanotechnology

Half-Metallic Ferromagnetism and Surface Functionalization-Induced Metal-Insulator Transition in Graphene-like Two-Dimensional Cr2C Crystals

Chen Si et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Article Nanoscience & Nanotechnology

Monolayer Ti2CO2: A Promising Candidate for NH3 Sensor or Capturer with High Sensitivity and Selectivity

Xue-fang Yu et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

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Article Biophysics

TiO2 nanoparticle modified organ-like Ti3C2 MXene nanocomposite encapsulating hemoglobin for a mediator-free biosensor with excellent performances

Fen Wang et al.

BIOSENSORS & BIOELECTRONICS (2015)

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Article Physics, Multidisciplinary

Role of the surface effect on the structural, electronic and mechanical properties of the carbide MXenes

Xian-Hu Zha et al.

EPL (2015)

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Article Nanoscience & Nanotechnology

Molecular dynamic study of the mechanical properties of two-dimensional titanium carbides Tin+1Cn (MXenes)

Vadym N. Borysiuk et al.

NANOTECHNOLOGY (2015)

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Article Chemistry, Physical

Flexible two-dimensional Tin+1Cn (n=1, 2 and 3) and their functionalized MXenes predicted by density functional theories

Zhonglu Guo et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

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Article Electrochemistry

An Organ-Like Titanium Carbide Material (MXene) with Multilayer Structure Encapsulating Hemoglobin for a Mediator-Free Biosensor

Fen Wang et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2015)

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Article Chemistry, Multidisciplinary

Nitrogen-doped carbon dots as fluorescent probe for detection of curcumin based on the inner filter effect

Qingyan Zhang et al.

RSC ADVANCES (2015)

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Article Chemistry, Multidisciplinary

Strain engineering of selective chemical adsorption on monolayer MoS2

Liangzhi Kou et al.

NANOSCALE (2014)

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Article Physics, Condensed Matter

Electronic and optical properties of 2D graphene-like compounds titanium carbides and nitrides: DFT calculations

H. Lashgari et al.

SOLID STATE COMMUNICATIONS (2014)

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Article Chemistry, Analytical

Chitosan-modified graphene electrodes for DNA mutation analysis

Subbiah Alwarappan et al.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2012)

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Review Chemistry, Multidisciplinary

Stabilization and functionalization of iron oxide nanoparticles for biomedical applications

Esther Amstad et al.

NANOSCALE (2011)

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Article Chemistry, Multidisciplinary

The Effect of Electrochemical Pretreatment on the Sensing Performance of Single Walled Carbon Nanotubes

Subbiah Alwarappan et al.

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY (2009)

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