期刊
BIORESOURCE TECHNOLOGY
卷 351, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2022.127031
关键词
Hydrothermal liquefaction; Hydrothermal carbonization; Bio-crude; Rice straw; Hydrochar; Seawater; Wastewater
资金
- Department of Science and Tech-nology (DST) , India [DST/TDT/WMT/AgWaste/2021/15]
- DST, India
- Ministry of Education, Govt. of India
This study focuses on the hydrothermal liquefaction (HTL) and carbonization (HTC) of rice straw using water from various sources. The results show that industrial wastewater yields the highest bio-crude production, while seawater yields the highest hydrochar production.
The need for fresh water limits the application and scale-up of hydrothermal technologies to convert waste biomass to energy and chemicals. In an effort to demonstrate the use of wastewater for sustainable process development, this work is focused on hydrothermal liquefaction (HTL) (350 degrees C, 18 MPa, 30 min) and carbonization (HTC) (200 degrees C, 7 MPa, 4 h) of rice straw with water from various sources (milli-Q water, tap water, seawater, recycled wastewater and industrial wastewater). The bio-crude yield from HTL was maximum (36.4 wt %) with industrial wastewater, while the yield of hydrochar from HTC was maximum (74.5 wt%) with seawater. The ions like K+, PO43- and NH4+ accumulated in the aqueous phase from rice straw. The hydrochars from HTL experiments contained significantly higher amount of ash compared to that from HTC experiments. Cyclopentenones and phenols were the major constituents of the bio-crude, whose HHV was 26.3 MJ/kg using seawater.
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