Heteroleptic metallosupramolecular aggregates/complexation for supramolecular catalysis

Supramolecular catalysis is reviewed with an eye on heteroleptic aggregates/complexation. Since most of the current metallosupramolecular catalytic systems are homoleptic in nature, the idea of breaking/reducing symmetry has ignited a vivid search for heteroleptic aggregates that are made up by different components. Their higher degree of functional diversity and structural heterogeneity allows, as demonstrated by Nature by the multicomponent ATP synthase motor, a more detailed and refined configuration of purposeful machinery. Furthermore, (metallo)supramolecular catalysis is shown to extend beyond the single supramolecular unit and to reach far into the field and concepts of systems chemistry and information science.

Automated summary

Current trend in supramolecular catalysis focuses on exploring heteroleptic aggregates composed of different components to achieve higher functional diversity and structural heterogeneity. This trend not only extends into the fields of systems chemistry and information science, but also provides more detailed and refined configuration plans.