4.7 Article

Role of the metal supply pathway on silicon patterning by oblique ion beam sputtering

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APPLIED SURFACE SCIENCE
卷 580, 期 -, 页码 -

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DOI: 10.1016/j.apsusc.2021.152267

关键词

Surface nanopatterning; Ion beam sputtering; Silicon; Magnetic properties; Silicides; Iron

资金

  1. Spanish MINECO [MAT2016-80394-R, PID2020-113142RB-C21]
  2. TRANS-NANOAVANSENS program from the Comunidad de Madrid [S2018/NMT-4349]
  3. Ramon y Cajal program [RYC-2015-18047]
  4. A.E. Consejo Superior de Investigaciones Cientificas [CSIC-2019AEP150]
  5. Spanish Ministerio de Ciencia e Innovacion and Consejo Superior de Investigaciones Cientificas [2010 6 0E 013, PIE 2021 60 E 030]

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This paper investigates the dynamics of the pattern induced on a silicon surface by oblique incidence of a 40 keV Fe ion beam. The results show that the Fe-induced pattern differs from two reference systems and exhibits a short hexagonal ordering structure. The metal pathway plays a critical role in determining the morphological, chemical, and magnetic properties of the patterns.
The dynamics of the pattern induced on a silicon surface by oblique incidence of a 40 keV Fe ion beam is studied. The results are compared with those obtained for two reference systems, namely a noble gas ion beam either without or with Fe co-deposition. The techniques employed include Atomic Force Microscopy, Rutherford Backscattering Spectrometry, Transmission Electron Microscopy, X-ray Photoelectron and hard X-ray photoelectron spectroscopies, as well as Superconducting Quantum Interference Device measurements. The Fe-induced pattern differs from those of both reference systems since a pattern displaying short hexagonal ordering develops, although it shares some features with them. In both Fe systems a chemical pattern, with iron silicide-rich and -poor regions, is formed upon prolonged irradiation. The metal pathway has a marked influence on the patterns' morphological properties and on the spatial correlation between the chemical and morphological patterns. It also determines the iron silicide stoichiometry and the surface pattern magnetic properties that are better for the Feimplanted system. These results show that in ion-beam-induced silicon surface patterning with reactive metals, the metal supply pathway is critical to determine not only the morphological pattern properties, but also the chemical and magnetic ones.

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