期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 36, 期 8, 页码 -出版社
WILEY
DOI: 10.1002/aoc.6775
关键词
coupling reaction; MOF; MOF@COF hybrid material; palladium catalyst
资金
- National Natural Science Foundation of China [21962017, 31760608, 21968032]
- Key laboratory for Utility of Environmental Friendly Composite Materials and Biomass in University of Gansu Province (Northwest Minzu University)
- Northwest Minzu University [1110130141, 1110130139]
- Training Plan for college students' Scientific Research ability of Lanzhou University of Arts and Sciences [2021DXSKY32]
- National Innovation and Entrepreneurship Program for University students, Innovation and Entrepreneurship Program for University students in Gansu Province [S202111562004]
A novel porous composite material MOF@COF has been successfully constructed and applied in the field of catalysis, showing high stability and catalytic activity, making it an excellent catalyst support material.
A novel type of porous composites MOF@COF was successfully constructed through decorating covalent organic framework (COF) crystals on the surface of amino-functionalized metal organic framework (NH2-MOF). This material has proven to be an excellent catalyst support because it not only overcomes the shortcoming of MOF instability but also combines the advantages of both high specific surface areas. Pd (OAc)(2) is anchored on MOF@COF to obtain MOF@COF-Pd catalyst. MOF@COF-Pd is used to catalyze the C-C coupling reaction of pyrimidine sulfonate and aryl boronic acid. The catalyst has the advantages of high stability, catalytic activity, recyclability, and no metal loss. And the application of MOF@COF hybrid materials was expanded in the field of catalysis.
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