4.7 Article

Remarkable stability of dye in polymer-clay nanocomposite film

期刊

APPLIED CLAY SCIENCE
卷 218, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.clay.2021.106405

关键词

Dye stability; Thermal stability; Irradiation at elevated temperature; Clay; Polyvinylpyrrolidone

资金

  1. Program Management Unit for Human Resources & Institutional Development, Research and Innovation, NXPO [B05F630117]
  2. National Science and Technology Development Agency (NSTDA), Thailand,\ [FDA-CO-2560-5655]
  3. National Research Council of Thailand (NRCT) [N41A640072]
  4. New Energy and Industrial Technology Development Organization (NEDO), Japan [JPNP18016]
  5. Vidyasirimedhi Institute of Science and Technology (VISTEC)

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This study investigated the immobilization of rhodamine 6G and polyvinylpyrrolidone in purified bentonite. The successful intercalation of the dyes and polymer into the interlayer space of the bentonite was confirmed, and superior stability was observed under heating and sunlight irradiation conditions.
The immobilization of rhodamine 6G and polyvinylpyrrolidone in a purified bentonite was investigated. Hybrid films were prepared by mixing an aqueous rhodamine 6G-bentonite suspension with aqueous solution of polyvinylpyrrolidone and subsequent casting on the solid substrate. The successful intercalation of the dyes and the polymer into the interlayer space of the bentonite was confirmed by the systematic expansion of the interlayer space. The stability of the rhodamine 6G adsorbed on the purified bentonite with polyvinylpyyrolidone was examined by following the appearance and the spectroscopic characteristics to find superior stabilities upon heating at 300 degrees C and sunlight irradiation at 150 degrees C in air if compared with the dye on the purified bentonite (without polymer) and that in the polymer (without bentonite).

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