期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 307, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2022.121174
关键词
Electric-assisted photocatalysis; Carrier separation; Water splitting; H(2)O(2 )synthesis; Self-doped TiO2 nanotube film; CO2 photoreduction
资金
- National Key Research and Development Program of China [2020YFC1908704]
- International Science & Technology Cooperation Program of China [2016YFE0126300]
- National Natural Science Foundation of China [52070082]
This study developed an electric-assisted photocatalytic technique to reduce carrier recombination induced by doping, resulting in a remarkable improvement in charge carrier dynamics.
Semiconductor doping is an effective strategy for improving the light absorption efficiency and the photo generated carrier transport in photocatalysts. However, bulk defects induced by doping act as recombination centers, accelerating the recombination of carriers, which is detrimental to the photocatalytic performance. In this study, a novel electric-assisted photocatalytic technique was developed to reduce the recombination of the carriers trapped by the defects. The technique involves applying a low external voltage to a self-doped TiO2 nanotube film, without any electrolyte and counter electrode. The remarkable improvement in the charge carrier dynamics under the electric assistance is attributed to the significant promotion of photogenerated electron fluxes and prevention of charge recombination. The electric-assisted photocatalytic technique is compatible with a liquid-or a gas-phase reactive system, e.g., water splitting, H2O2 synthesis, and CO2 photoreduction. The technique is sufficiently advanced to allow scale-up of the photocatalytic process from laboratory scale to industrial-scale.
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