4.8 Article

Self-Regulating Colloidal Co-Assemblies That Accelerate Their Own Destruction via Chemo-Structural Feedback

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

Carbodiimide-fueled catalytic reaction cycles to regulate supramolecular processes

Patrick S. Schwarz et al.

Summary: This article discusses the method of using a reaction cycle that converts chemical energy to regulate molecular self-assembly, and proposes the idea of designing carbodiimide-driven reaction cycles to create desired morphology or function of the assembly.

CHEMICAL COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

Autonomous Transient pH Flips Shaped by Layered Compartmentalization of Antagonistic Enzymatic Reactions

Xinlong Fan et al.

Summary: This study demonstrates the programming of transient pH signals using layered compartments containing antagonistic pH-modulating enzymes, overcoming limitations of activity mismatches in solution. Precise programming of pH lifecycles is achieved by adjusting spatial and kinetic conditions, allowing for flexible control of acidic and alkaline pH phases.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Chemically Fueled Volume Phase Transition of Polyacid Microgels

Jonas Heckel et al.

Summary: This study introduces chemically fueled transient volume phase transitions for PMAA microgels, demonstrating controlled system behavior as a function of pH and fuel amount. Additionally, the technology showcased potential applications in transient encapsulation and time-programmed release.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

pH Feedback Lifecycles Programmed by Enzymatic Logic Gates Using Common Foods as Fuels

Xinlong Fan et al.

Summary: This study demonstrates a method to program temporal pH signals by enzymatic logic gates, utilizing enzymatic reaction networks catalyzed by invertase-glucose oxidase and beta-galactosidase-glucose oxidase. The system is robust in operating with all-food grade chemicals and coupling to self-regulating hydrogel in unknown components medium and biocompatible fashion.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Feedback and Communication in Active Hydrogel Spheres with pH Fronts: Facile Approaches to Grow Soft Hydrogel Structures

Indrajit Maity et al.

Summary: This study compartmentalizes urea-urease and ester-esterase reaction networks into hydrogel spheres to investigate fuel-driven pH fronts release and regulation mechanisms. The findings can be applied to self-growing hydrogels and developing complex geometries from non-injectable hydrogels.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Substrate induced generation of transient self-assembled catalytic systems

Syed Pavel Afrose et al.

Summary: Living matter sustains itself under non-equilibrium conditions by continuously expending energy through complex organized events. Control over exquisite functions arises from chemical complexity, leading to acceleration of catalytic rates through substrate binding events. The concept of substrate-induced self-assembly and rate acceleration has the potential to play a predominant role in preparing non-equilibrium systems.

CHEMICAL SCIENCE (2021)

Article Multidisciplinary Sciences

Autonomous DNA nanostructures instructed by hierarchically concatenated chemical reaction networks

Jie Deng et al.

Summary: The study reports ATP-fueled autonomous DNA nanotube assembly regulated by DNA strand displacement reactions, which are induced and controlled by an upstream enzyme reaction network of concurrent ATP-mediated ligation and restriction of DNA components. The concatenation and communication between chemically distinct chemical reaction networks is essential for controlling dynamics of hierarchical structures. This study provides a model system for biological systems by demonstrating autonomous lifecycles of DNA nanotubes through two concatenated CRNs using different thermodynamic principles.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Multidisciplinary

Chemically Fueled Block Copolymer Self-Assembly into Transient Nanoreactors**

Michaela A. Wuerbser et al.

Summary: Researchers designed a diblock copolymer that self-assembles into transient micelles when combined with a fuel-driven chemical reaction cycle, allowing for localized increase in hydrophobic reagent concentration and functioning as a transient nanoreactor.

CHEMSYSTEMSCHEM (2021)

Article Chemistry, Physical

Spinodal decomposition of chemically fueled polymer solutions

Jonas Heckel et al.

Summary: This study investigates the chemically fueled spinodal decomposition process driven by a cyclic chemical reaction network, examining the morphology of formed domains, kinetics, and mechanism of domain growth. A kinetic/thermodynamic hybrid model was developed to rationalize the system's dependence on fuel concentration and pH, providing insights into predictive design of future fueled polymer systems.

SOFT MATTER (2021)

Article Chemistry, Multidisciplinary

Pathway Complexity in Fuel-Driven DNA Nanostructures with Autonomous Reconfiguration of Multiple Dynamic Steady States

Jie Deng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Covalent Catalysis by Cross β Amyloid Nanotubes

Baishakhi Sarkhel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

ATP-Responsive and ATP-Fueled Self-Assembling Systems and Materials

Jie Deng et al.

ADVANCED MATERIALS (2020)

Article Multidisciplinary Sciences

Pathways and challenges towards a complete characterization of microgels

Frank Scheffold

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Programmable dynamic steady states in ATP-driven nonequilibrium DNA systems

Laura Heinen et al.

SCIENCE ADVANCES (2019)

Article Chemistry, Multidisciplinary

Chemically Fueled Dissipative Self-Assembly that Exploits Cooperative Catalysis

Subhajit Bal et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Adenosine-Phosphate-Fueled, Temporally Programmed Supramolecular Polymers with Multiple Transient States

Shikha Dhiman et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Review Polymer Science

Field responsive materials: photo-, electro-, magnetic- and ultrasound-sensitive polymers

Theodore Manouras et al.

POLYMER CHEMISTRY (2017)

Article Multidisciplinary Sciences

Non-equilibrium steady states in supramolecular polymerization

Alessandro Sorrenti et al.

NATURE COMMUNICATIONS (2017)

Review Chemistry, Multidisciplinary

Materials learning from life: concepts for active, adaptive and autonomous molecular systems

Remi Merindol et al.

CHEMICAL SOCIETY REVIEWS (2017)

Article Chemistry, Multidisciplinary

Social Self-Sorting of Colloidal Families in Co-Assembling Microgel Systems

Kang Han et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Functional Microgels and Microgel Systems

Felix A. Plamper et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

Article Chemistry, Multidisciplinary

Dissipative self-assembly of vesicular nanoreactors

Subhabrata Maiti et al.

NATURE CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Biocatalytic Feedback-Driven Temporal Programming of Self-Regulating Peptide Hydrogels

Thomas Heuser et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Insight into the esterase like activity demonstrated by an imidazole appended self-assembling hydrogelator

Nishant Singh et al.

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

Light-Triggered Capture and Release of DNA and Proteins by Host-Guest Binding and Electrostatic Interaction

Johanna Moratz et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Multidisciplinary Sciences

Transient assembly of active materials fueled by a chemical reaction

Job Boekhoven et al.

SCIENCE (2015)

Article Multidisciplinary Sciences

Transient signal generation in a self-assembled nanosystem fueled by ATP

Cristian Pezzato et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Multidisciplinary

Generic Concept to Program the Time Domain of Self-Assemblies with a Self-Regulation Mechanism

Thomas Heuser et al.

NANO LETTERS (2015)

Review Biotechnology & Applied Microbiology

Materials-Based Strategies for Multi-Enzyme Immobilization and Co-Localization: A Review

Feng Jia et al.

BIOTECHNOLOGY AND BIOENGINEERING (2014)

Article Chemistry, Multidisciplinary

Self-assembly and applications of poly(glycidyl methacrylate)s and their derivatives

Qing-Lan Li et al.

CHEMICAL COMMUNICATIONS (2014)

Article Biotechnology & Applied Microbiology

Enzyme clustering accelerates processing of intermediates through metabolic channeling

Michele Castellana et al.

NATURE BIOTECHNOLOGY (2014)

Article Chemistry, Multidisciplinary

Macroscopic self-assembly through molecular recognition

Akira Harada et al.

NATURE CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel

Job Boekhoven et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Review Chemistry, Physical

Emerging applications of stimuli-responsive polymer materials

Martien A. Cohen Stuart et al.

NATURE MATERIALS (2010)

Article Chemistry, Multidisciplinary

Autonomously Oscillating Viscosity in Microgel Dispersions

Daisuke Suzuki et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

Self-flocculating/Self-dispersing oscillation of microgels

Daisuke Suzuki et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Review Biotechnology & Applied Microbiology

Glucose oxidase: natural occurrence, function, properties and industrial applications

Chun Ming Wong et al.

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY (2008)

Review Cell Biology

Molecular architecture of the kinetochore-microtubule interface

Iain M. Cheeseman et al.

NATURE REVIEWS MOLECULAR CELL BIOLOGY (2008)

Article Multidisciplinary Sciences

Reversible self-assembly and directed assembly of DNA-linked micrometer-sized colloids

MP Valignat et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2005)

Article Multidisciplinary Sciences

Self-assembly at all scales

GM Whitesides et al.

SCIENCE (2002)