☆ 4.8 Article

Gadolinium Changes the Local Electron Densities of Nickel 3d Orbitals for Efficient Electrocatalytic CO2 Reduction

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Physical

Rare earth La single atoms supported MoO3-x for efficient photocatalytic nitrogen fixation

Xiufan Liu et al.

Summary: The rare-earth La single catalyst, with a well-designed coordination structure, shows excellent catalytic performance in hydrogenation and photocatalysis for nitrogen fixation under visible light, outperforming most reported single atom photocatalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

添加到收藏夹

Article Engineering, Environmental

A Ni nanoparticles encapsulated in N-doped carbon catalyst for efficient electroreduction CO2: Identification of active sites for adsorption and activation of CO2 molecules

Fangyuan Wang et al.

Summary: The study developed an efficient Ni@N-C/rGO catalyst for CO2 reduction to CO, showing high catalytic activity, selectivity, and stability. Poisoning and control experiments confirmed that the catalytic activity originates from the N-doped carbon layer, with DFT calculations revealing pyrrolic-N as the optimal active site for CO2 adsorption and activation.

CHEMICAL ENGINEERING JOURNAL (2022)

添加到收藏夹

Article Chemistry, Physical

Optimization of pH-universal O2 reduction electrocatalysis by precise control over structural variables via basic bathing

Chuangchuang Yang et al.

Summary: Biomass-based catalysts show promise as alternatives to Pt for ORR, but optimization requires tuning structural variables, enhancing mass transport, and achieving pH-universal catalytic activities. The 'basic bathing' method allows precise control over the structure of nitrogen-doped metal-free ORR electrocatalysts, leading to improved performance and pH-universal catalytic activity. Results indicate the importance of mesopores and nitrogen species distributions in enhancing pH-universal ORR performance.

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY (2022)

添加到收藏夹

Article Chemistry, Physical

Charge localization to optimize reactant adsorption on KCu7S4/CuO interfacial structure toward selective CO2 electroreduction

Lin Lv et al.

Summary: The novel KCu7S4/CuO interfacial structure induced the formation of localized charge region to optimize the adsorption properties of active intermediates, promoting CO2 electroreduction with enhanced activity and selectivity towards formate.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Physical

Electron density modulation of MoP by rare earth metal as highly efficient electrocatalysts for pH-universal hydrogen evolution reaction

Peng Wei et al.

Summary: Molybdenum phosphide (MoP) is a promising hydrogen evolution reaction (HER) catalyst, and doping with rare earth metals such as La and Yb can effectively regulate its electronic structure, improving both activity and durability in a wide pH range. This research enriches RE-modified catalysts and demonstrates the potential of RE metal doping as a general method for enhancing the performance of non-noble metal catalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Physical

Robust coal matrix intensifies electron/substrate interaction of nickel-nitrogen (Ni-N) active sites for efficient CO2 electroreduction at industrial current density

Weiqi Liu et al.

Summary: Using anthracite coal as a catalyst support in electrocatalytic reduction of CO2 has shown promising results, with the formation of micropores to enhance the quantity of nickel-nitrogen active sites, facilitating electron/substrate interaction and improving current density and stability in CO production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Physical

Boosting electrochemical performance of activated carbon by tuning effective pores and synergistic effects of active species

Peiyao Bai et al.

Summary: A promising NPC material with excellent electrochemical performance has been successfully synthesized in this work, with delicately tuned pore structures and nitrogen species. Compared to traditional materials, this material exhibits outstanding performance in both oxygen reduction reaction and supercapacitors, demonstrating the synergistic effects of nitrogen species and optimized pore structures.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dual Functions of CO2 Molecular Activation and 4f Levels as Electron Transport Bridge in Dysprosium Single Atom Composite Photocatalysts with Enhanced Visible-Light Photoactivities

Yue Zhao et al.

Summary: The study successfully constructed Dy3+ single atom composite photocatalysts and achieved significant enhancement of photocatalytic activity by providing an efficient electron transfer pathway and fully utilizing the characteristics of rare-earth single atoms and 4f levels.

ADVANCED FUNCTIONAL MATERIALS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Efficient Electroconversion of Carbon Dioxide to Formate by a Reconstructed Amino-Functionalized Indium-Organic Framework Electrocatalyst

Zhitong Wang et al.

Summary: The amino-functionalized indium-organic framework catalyst enhances the absorption and activation of CO2, leading to an improved catalytic conversion to formate. The reconstructed catalyst achieves high Faradaic efficiency and current density, demonstrating valuable insights for CO2 electrocatalysis and reactor optimization.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

The Controllable Reconstruction of Bi-MOFs for Electrochemical CO2 Reduction through Electrolyte and Potential Mediation

Dazhi Yao et al.

Summary: This study investigates the reconstruction of a Bi-based metal-organic framework for electrochemical CO2 reduction, demonstrating that controlling the intricate reconstruction process results in excellent activity and stability of the Bi catalyst, shedding light on the design of highly efficient electrocatalysts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Atomically Dispersed s-Block Magnesium Sites for Electroreduction of CO2 to CO

Qiyou Wang et al.

Summary: This study demonstrates the construction of atomically dispersed magnesium atoms embedded in graphitic carbon nitride for CO2 electroreduction to CO. Theoretical calculations and experimental results show that the desorption of CO on Mg sites is easier compared to Fe and Co sites, leading to higher CO Faradaic efficiency and activity. This work sheds new light on the use of s-block metal sites for efficient CO2RR.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Physical

Long-range order, short-range disorder: Engineering one-dimensional flow channel arrays with hierarchically porous reaction interfaces for electrocatalytic reduction of oxygen

Wendu Zhang et al.

Summary: Fuel cell performance relies on electrochemical reaction kinetics and mass transport, with an emphasis on the latter in this work. Using the concept of 'long-range order, short-range disorder', the study successfully enhanced both reaction kinetics and mass transport performance.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Physical

Comprehensive Mechanism of CO2 Electroreduction toward Ethylene and Ethanol: The Solvent Effect from Explicit WaterCu(100) Interface Models

Jirapat Santatiwongchai et al.

Summary: This study presents a comprehensive CO2 electro-reduction mechanism on a Cu(100) surface using density functional theory simulations, revealing various favorable alternative pathways and elucidating each step of the CO2 conversion to CO process. The results offer guidance on tuning the selectivity of ethylene and ethanol, and provide insights into the solvent effect on intermediates involved in CO2 electroreduction.

ACS CATALYSIS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Electrode Materials Engineering in Electrocatalytic CO2 Reduction: Energy Input and Conversion Efficiency

Rong-Bin Song et al.

ADVANCED MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fluorine Doped Cagelike Carbon Electrocatalyst: An Insight into the Structure-Enhanced CO Selectivity for CO2 Reduction at High Overpotential

Wei Ni et al.

ACS NANO (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Controlled Synthesis of a Vacancy-Defect Single-Atom Catalyst for Boosting CO2 Electroreduction

Xin Rong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Understanding the Origin of Highly Selective CO2 Electroreduction to CO on Ni,N-doped Carbon Catalysts

David M. Koshy et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrochemical Conversion of CO2 to Syngas with Controllable CO/H2 Ratios over Co and Ni Single-Atom Catalysts

Qun He et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Physical

Highly Selective Reduction of CO2 to C2+ Hydrocarbons at Copper/Polyaniline Interfaces

Xing Wei et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Physical

Activation of Ni Particles into Single Ni-N Atoms for Efficient Electrochemical Reduction of CO2

Qun Fan et al.

ADVANCED ENERGY MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Boosting CO2 Electroreduction on N,P-Co-doped Carbon Aerogels

Chunjun Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Atomically Dispersed Nickel(I) on an Alloy-Encapsulated Nitrogen-Doped Carbon Nanotube Array for High-Performance Electrochemical CO2 Reduction Reaction

Tianyu Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Multidisciplinary Sciences

Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks

Haixia Zhong et al.

NATURE COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Size-Dependent Nickel-Based Electrocatalysts for Selective CO2Reduction

Zhida Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Physical

Utilizing spatial confinement effect of N atoms in micropores of coal-based metal-free material for efficiently electrochemical reduction of carbon dioxide

Weiqi Liu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

添加到收藏夹

Article Acoustics

Ultrasound-assisted transformation from waste biomass to efficient carbon-based metal-free pH-universal oxygen reduction reaction electrocatalysts

Huifen Wang et al.

ULTRASONICS SONOCHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Physical

Solvent-free synthesis of N-doped nanoporous carbon materials as durable high-performance pH-universal ORR catalysts

Lejian Yu et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2020)

添加到收藏夹

Article Chemistry, Physical

Low-temperature strategy toward Ni-NC@Ni core-shell nanostructure with Single-Ni sites for efficient CO2 electroreduction

Yu He et al.

NANO ENERGY (2020)

添加到收藏夹

Article Chemistry, Physical

Zn-Modified Co@N-C composites with adjusted Co particle size as catalysts for the efficient electroreduction of CO2

Zhichao Miao et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

添加到收藏夹

Article Chemistry, Physical

Nitrogen-doped porous carbon from coal for high efficiency CO2 electrocatalytic reduction

Chen Li et al.

CARBON (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electroreduction of CO2 catalyzed by Co@N-C materials

Weiqi Liu et al.

JOURNAL OF CO2 UTILIZATION (2019)

添加到收藏夹

Article Chemistry, Physical

Promoting electrocatalytic CO2 reduction on nitrogen-doped carbon with sulfur addition

Fuping Pan et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

添加到收藏夹

Article Chemistry, Physical

Highly active metallic nickel sites confined in N-doped carbon nanotubes toward significantly enhanced activity of CO2 electroreduction

Wanzhen Zheng et al.

CARBON (2019)

添加到收藏夹

Review Energy & Fuels

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

Yuvraj Y. Birdja et al.

NATURE ENERGY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Efficient Electrosynthesis of Syngas with Tunable CO/H2 Ratios over ZnxCd1-xS-Amine Inorganic-Organic Hybrids

Nannan Meng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Multidisciplinary Sciences

A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts

Hongzhou Yang et al.

NATURE COMMUNICATIONS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Template-free preparation of anthracite-based nitrogen-doped porous carbons for high-performance supercapacitors and efficient electrocatalysts for the oxygen reduction reaction

Jiawei Qi et al.

RSC ADVANCES (2019)

添加到收藏夹

Review Chemistry, Physical

Emerging nanostructured carbon-based non-precious metal electrocatalysts for selective electrochemical CO2 reduction to CO

Xinyue Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Surface Immobilization of Transition Metal Ions on Nitrogen-Doped Graphene Realizing High-Efficient and Selective CO2 Reduction

Wentuan Bi et al.

ADVANCED MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction

Yi Cheng et al.

ADVANCED MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Metal-Free Fluorine-Doped Carbon Electrocatalyst for CO2 Reduction Outcompeting Hydrogen Evolution

Jiafang Xie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Article Chemistry, Physical

Methane steam reforming in water deficient conditions on Ir/Ce0.9Gd0.1O2-x catalyst: Metal-support interactions and catalytic activity enhancement

S. K. Cheah et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Coordinatively unsaturated nickel-nitrogen sites towards selective and high-rate CO2 electroreduction

Chengcheng Yan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

添加到收藏夹

Article Energy & Fuels

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

Hong Bin Yang et al.

NATURE ENERGY (2018)

添加到收藏夹

Article Chemistry, Physical

Tuning Structural and Compositional Effects in Pd-Au Nanowires for Highly Selective and Active CO2 Electrochemical Reduction Reaction

Shangqian Zhu et al.

ADVANCED ENERGY MATERIALS (2018)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.