期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 61, 期 25, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202117563
关键词
Carbonate; Electrochemistry; Oxidations; Peroxides; Peroxodicarbonate
资金
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany's Excellence [Strategy-EXC-2033-390677874-RESOLV, FOR 2982/1-UNODE]
- BMBF
- state of NRW (Center of Solvation Science ZEMOS)
- Forschungsinitiative Rheinland-Pfalz
- Projekt DEAL
Concentrated peroxodicarbonate solutions have been successfully prepared through electrolysis of carbonate solutions, and their synthetic potential has been demonstrated in various transformations.
Peroxodicarbonates are of substantial interest as potentially powerful and sustainable oxidizers but have so far been accessible only in low concentrations with unsatisfactory energy efficiency. Concentrated (> 0.9 mol L-1) peroxodicarbonate solutions have now been made accessible by the electrolysis of aqueous K2CO3/Na2CO3/KHCO3 solutions at high current density of 3.33 A cm(-2) in an efficiently cooled circular flow reactor equipped with a boron-doped diamond anode and a stainless-steel cathode. Their synthetic potential as platform oxidizers was clearly demonstrated in transformations including sulfoxidation, N-oxidation, and epoxidation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据