4.8 Article

Metathesis Reactions of a NHC-Stabilized Phosphaborene

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

Heavier group 13/15 multiple bond systems: synthesis, structure and chemical bond activation

F. Dankert et al.

Summary: Research on heavier group 13/15 multiple bonds has shown that they are synthetically feasible, leading to the creation of new compounds such as phospha- and arsaalumenes. These findings demonstrate the obsoleteness of the traditional double bond rule and highlight the synthetic potential of these chemical bonds.

CHEMICAL COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

A Mixed Heavier Si=Ge Analogue of a Vinyl Anion

Paresh Kumar Majhi et al.

Summary: The synthesis and isolation of a stable potassium silagermenide compound with a Si=Ge bond as a suitable synthon for functional silagermenes has been reported. X-ray crystallographic analysis, UV/Vis spectroscopy, and DFT calculations confirmed a significant degree of pi-conjugation between N=C and Si=Ge double bonds in the compound.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Inorganic & Nuclear

A Cyclic Iminoborane-NHC Adduct: Synthesis, Reactivity, and Bonding Analysis

Abhishek Koner et al.

Summary: A new synthetic strategy was developed to prepare a highly stable cyclic amino iminoborane carbene complex, showing unprecedented thermal stability. Furthermore, the formation of the chemical bond can be explained as a donor-acceptor interaction, resulting in a different electronic structure of the B=N pi-bond.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Boraiminolithium: An Iminoborane-Transfer Reagent

Rui Guo et al.

Summary: The BN/CC isosterism can create unique molecules with attractive properties. The boraiminolithium species 2, a room-temperature-stable crystalline solid, shows remarkable reactivity in iminoborane-transfer reactions, leading to the synthesis of unprecedented N-functionalized iminoboranes and novel main-group heterocycles. These stable boraiminolithium reagents have the potential to be powerful tools for exploring new BN-containing building blocks in synthetic chemistry and materials science.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

A Cyaphide Transfer Reagent

Daniel W. N. Wilson et al.

Summary: The cyanide ion plays a key role in industrially relevant chemical processes, but heavier cyanide analogues are largely unexplored due to a lack of suitable synthesis methods.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

The Phospha-Bora-Wittig Reaction

Andryj M. Borys et al.

Summary: The phospha-bora-Wittig reaction allows for the direct preparation of phosphaalkenes from aldehydes, ketones, esters, or amides, through the intermediate formation of 1,2,3-phosphaboraoxetanes. Experimental and density functional theory studies have revealed far-reaching similarities between the classical and phospha-bora-Wittig reactions, shedding light on the reaction mechanism.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Inorganic & Nuclear

Synthesis of the Cyclic Group 13 Phosphinidenides [(NHC)PMCl2]2 (NHC = SIMes, SIDipp; M = Al, Ga)

Markus Balmer et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2020)

Article Chemistry, Multidisciplinary

Crystalline BP-Doped Phenanthryne via Photolysis of The Elusive Boraphosphaketene

Wenlong Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Isolation of a 1-Magnesium-2,3-disilacyclopropene and a Related Bis(disilenide)

Miao Tian et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene Analogues of Nucleophilic Phosphinidene Transition Metal Complexes

Adinarayana Doddi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Review Chemistry, Multidisciplinary

N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry

Adinarayana Doddi et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Inorganic & Nuclear

Isolation and Reactivity of a Digerma Analogue of Vinyllithiums: a Lithium Digermenide

David Nieder et al.

ORGANOMETALLICS (2018)

Review Chemistry, Multidisciplinary

Energy decomposition analysis

Lili Zhao et al.

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2018)

Review Chemistry, Multidisciplinary

The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications

Zachary X. Giustra et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Inorganic & Nuclear

New Group 14 Element Substituted Phosphaalkenes

Markus Balmer et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2018)

Article Chemistry, Inorganic & Nuclear

N-Heterocyclic Carbene-Phosphinidene and Carbene-Phosphinidenide Transition Metal Complexes

Marius Peters et al.

INORGANIC CHEMISTRY (2017)

Review Chemistry, Multidisciplinary

London dispersion forces in sterically crowded inorganic and organometallic molecules

David J. Liptrot et al.

NATURE REVIEWS CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Phosphaborenes: Accessible Reagents for the Synthesis of C-C/P-B Isosteres

Amy N. Price et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Multidisciplinary

Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

Carsten Praesang et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Base-Stabilized Phosphinidene Boranes by Silylium-Ion Abstraction

Amy N. Price et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Article Chemistry, Multidisciplinary

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

J. Philipp Wagner et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Phosphinidene Complexes of the Coinage Metals

Adinarayana Doddi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Review Chemistry, Organic

Recent developments and applications of the Cadiot-Chodkiewicz reaction

K. S. Sindhu et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

BN Heterosuperbenzenes: Synthesis and Properties

Xiao-Ye Wang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Phosphinidyne Transition Metal Complexes

Adinarayana Doddi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Review Chemistry, Multidisciplinary

Recent Advances in Azaborine Chemistry

Patrick G. Campbell et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Transmetallation reactions of a lithium disilenide

Michael J. Cowley et al.

CHEMICAL COMMUNICATIONS (2012)

Review Chemistry, Multidisciplinary

B-N as a C-C substitute in aromatic systems

Michael J. D. Bosdet et al.

CANADIAN JOURNAL OF CHEMISTRY (2009)

Article Chemistry, Multidisciplinary

Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition

Takeaki Iwamoto et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Article Chemistry, Multidisciplinary

An isolable disilyne anion radical and a new route to the disilenide ion upon reduction of a disilyne

Rei Kinjo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

Review Chemistry, Multidisciplinary

The sonogashira reaction: A booming methodology in synthetic organic chemistry

Rafael Chinchilla et al.

CHEMICAL REVIEWS (2007)

Review Chemistry, Multidisciplinary

Phosphorus copies of PPV:: π-conjugated polymers and molecules composed of alternating phenylene and phosphaalkene moieties

Vincent A. Wright et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

Article Chemistry, Multidisciplinary

A donor-stabilization strategy for the preparation of compounds featuring P=B and As=B double bonds

Eric Rivard et al.

CHEMICAL COMMUNICATIONS (2006)

Article Chemistry, Multidisciplinary

Activation of a Si=Si bond by η1-coordination to a transition metal

TL Nguyen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Review Chemistry, Inorganic & Nuclear

Recent developments in the chemistry of metallophosphaalkenes

L Weber

COORDINATION CHEMISTRY REVIEWS (2005)

Article Chemistry, Inorganic & Nuclear

Disilenyllithium from tetrasila-1,3-butadiene: A silicon analogue of a vinyllithium

M Ichinohe et al.

ORGANOMETALLICS (2004)

Article Chemistry, Multidisciplinary

A silicon analogue of vinyllithium: Structural characterization of a disilenide

D Scheschkewitz

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

Review Chemistry, Multidisciplinary

The electrophilic nature of carbenoids, nitrenoids, and oxenoids

G Boche et al.

CHEMICAL REVIEWS (2001)