Iridium and IrOx nanoparticles: an overview and review of syntheses and applications

Precious metals are key in various fields of research and precious metal nanomaterials are directly relevant for optics, catalysis, pollution management, sensing, medicine, and many other applications. Iridium based nano materials are less studied than metals like gold, silver or platinum. A specific feature of iridium nanomaterials is the relatively small size nanoparticles and clusters easily obtained, e.g. by colloidal syntheses. Progress over the years overcomes the related challenging characterization and it is expected that the knowledge on iridium chemistry and nanomaterials will be growing. Although Ir nanoparticles have been preferred systems for the development of kinetic-based models of nanomaterial formation, there is surprisingly little knowledge on the actual formation mechanism(s) of iridium nanoparticles. Following the impulse from the high expectations on Ir nanoparticles as catalysts for the oxygen evolution reaction in electrolyzers, new areas of applications of iridium materials have been reported while more established applications are being revisited. This review covers different synthetic strategies of iridium nanoparticles and provides an in breadth overview of applications reported. Comprehensive Tables and more detailed topic-oriented overviews are proposed in Supplementary Material, covering synthesis protocols, the historical role or iridium nanoparticles in the development of nanoscience and applications in catalysis.

Automated summary

Precious metal nanomaterials, including iridium-based nanomaterials, are widely used in various fields such as optics, catalysis, pollution management, sensing, and medicine. Despite the relatively small size and easy synthesis of iridium nanoparticles and clusters, there is still limited understanding of their formation mechanisms. This review provides an overview of synthetic strategies for iridium nanoparticles and discusses their applications. Supplementary material is also provided, including synthesis protocols, the historical role of iridium nanoparticles in nanoscience, and their applications in catalysis.