4.7 Article

Visible-Light-Induced Oxidation of Diazenyl-Protected Tetrahydroisoquinolines and Isoindolines for the Synthesis of Functionalized Lactams

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 364, 期 12, 页码 1962-1968

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202101506

关键词

Visible-Light-Induced; Oxidation; Triazenes; Molecular Oxygen; Lactams

资金

  1. Natural Science Foundation of Xinjiang Uyghur Autonomous Region [2021D01E10]
  2. NSFC [21861036, 21961037]
  3. Program for Tianshan Innovative Research Team of Xinjiang Uygur Autonomous Region [2021D14011]

向作者/读者索取更多资源

This paper describes a visible-light-induced chemical reaction that can synthesize structurally diverse lactams under mild and transition metal-free conditions. The utility of this method is showcased through gram-scale synthesis and deprotection.
A visible-light-induced oxidation of diazenyl-protected tetrahydroisoquinolines and isoindolines for the synthesis of structurally diverse lactams is developed. The reaction was carried out with Eosin Y-Na-2 as an organic photocatalyst and molecular oxygen as an oxidant, and the desired functionalized N-aryldiazenyl-lactams were obtained under mild and transition metal-free conditions. The utility of this method is showcased by the gram-scale synthesis and deprotection of the N-aryldiazenyl-lactam product.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据