期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 364, 期 9, 页码 1522-1525出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202200190
关键词
Benzamides; McFadyen-Stevens reaction; N-phthalimide; sulfoxide; sulfoximine
资金
- China Scholarship Council
- Projekt DEAL
Under mild conditions, an N-phthalimidoyl sulfoximine undergoes aminolysis to provide a wide range of 2-formyl benzamides in good to high yields. An unprecedented variant of McFadyen-Stevens reaction explains the product formation, and the applicability of the products as building blocks for nitriles and alkynes has been demonstrated.
Under mild conditions, an N-phthalimidoyl sulfoximine undergoes aminolysis to provide a wide range of 2-formyl benzamides in good to high yields. An unprecedented variant of McFadyen-Stevens reaction explains the product formation. The applicability of the products as building blocks for nitriles and alkynes has been demonstrated.
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