期刊
ADVANCED POWDER TECHNOLOGY
卷 33, 期 4, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apt.2022.103521
关键词
Lithium-sulfur batteries; Bi2S3; Reduced graphene oxide; Separator
资金
- National Natural Science Foundation of China [21706110]
- Joint Fund of Guangdong Basic and Applied Basic Research foundation [2019A1515110826]
- Youth Innovation Talent Project for the Universities of Guangdong [2018KTSCX131]
- Yanling Excellent Young Teacher Program of Lingnan Normal University [YL20200211, YL20200204]
- Special Talent Fund of Lingnan Normal University [ZL1804, ZL1805]
In this study, a flower-like Bi2S3/rGO modified separator was fabricated to alleviate the shuttle effect of polysulfide in Lithium-sulfur batteries (LSBs), resulting in improved reversible capacity and rate capacity.
A shuttle effect of polysulfide is one of the crucial barriers for Lithium-sulfur batteries (LSBs). Herein, a flower-like Bi2S3/reduced graphene oxide (rGO) modified separator was fabricated by simple solvothermal and filtration processes. Benefiting from the strong chemical capturing ability of flower-like Bi2S3 and conductive pathway derived from rGO, the modified separator obviously alleviated the polysulfide shuttling. The cell with the flower-like Bi2S3/rGO modified separator exhibits a reversible capacity of 600 mAh g(-1) at 0.5C after 300 cycles and a rate capacity of 500 mAh g-1 at 2C. (c) 2022 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan.
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