4.8 Review

Advances in SnO2 for Efficient and Stable n-i-p Perovskite Solar Cells

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Simultaneous Interfacial Modification and Crystallization Control by Biguanide Hydrochloride for Stable Perovskite Solar Cells with PCE of 24.4%

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Summary: In this study, a multifunctional interfacial material, BGCl, was introduced to modify the interface of perovskite solar cells. The BGCl improved electron extraction and crystal growth of perovskite by chemically linking to SnO2 and anchoring PbI2. This modification led to better energetic alignment, reduced interfacial defects, and homogeneous perovskite crystallites, resulting in highly efficient and stable performance.

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Conformal quantum dot-SnO2 layers as electron transporters for efficient perovskite solar cells

Minjin Kim et al.

Summary: The study replaced the commonly used mesoporous titanium dioxide electron transport layer with a thin layer of polyacrylic acid-stabilized tin(IV) oxide quantum dots, which improved the efficiency and stability of perovskite solar cells and enabled successful scaling up of PSCs production.

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Analytical Study of Solution-Processed Tin Oxide as Electron Transport Layer in Printed Perovskite Solar Cells

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Summary: Solution-processed tin oxide (SnOx) electron transport layers demonstrate excellent performance in various optoelectronic devices and offer the ease of deposition by various printing techniques. The properties of SnOx thin films have been investigated using various spectroscopies and microscopy techniques, showing improvements in structural and chemical properties with increasing annealing temperature. High performance perovskite solar cells with stabilized power conversion efficiency over 15% demonstrate the great potential of printed SnOx layers in solar energy applications.

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A synchronous defect passivation strategy for constructing high-performance and stable planar perovskite solar cells

Yansen Sun et al.

Summary: The study proposes a synchronous defect passivation strategy by introducing chelating agents with movable alkali metal cations into SnO2 aqueous colloidal dispersions, which effectively regulates the properties of ETL, perovskite layer, and their interface. This approach leads to uniform, less defective, and highly conductive ETLs, improving the interfacial charge transfer and resulting in high PCEs, reduced hysteresis, and improved stability for PSCs based on STA-SnO2 and PSTA-SnO2. This work simplifies the defect passivation process and provides a promising low-cost technique for large-scale manufacturing of efficient and stable planar PSCs.

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Batch chemical bath deposition of large-area SnO2 film with mercaptosuccinic acid decoration for homogenized and efficient perovskite solar cells

Jibo Zhang et al.

Summary: A modified double chemical bath deposition (DC) process was used to fabricate large-area tin oxide films for perovskite solar cells, leading to homogenized performance and improved efficiency, stability, and homogeneity of the devices. Introduction of mercaptosuccinic acid at the SnO2/perovskite interface further enhanced the power conversion efficiency, resulting in high efficiency perovskite devices. These findings suggest great potential for large-area and high efficiency perovskite module preparation using this modified CBD route.

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Morphological Effects in SnO2 Chemiresistors for Ethanol Detection: A Review in Terms of Central Performances and Outliers

Andrea Ponzoni

Summary: This study systematically compares the different SnO2 morphologies reported in literature in terms of response amplitude, with results indicating that none clearly outperform the others, while a few individual materials emerge as remarkable outliers. These observed central performances and outliers may serve as a suitable reference for future research activities in the field.

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Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth

Yeoun-Woo Jang et al.

Summary: Researchers have developed a solid-phase method to grow phase-pure two-dimensional perovskites in perovskite solar cells, enhancing device efficiency and stability. By growing a stable two-dimensional film on top of a three-dimensional film using a solvent-free method, an intact 2D/3D heterojunction is formed, resulting in high photovoltage in the device.

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Rubidium Fluoride Modified SnO2 for Planar n-i-p Perovskite Solar Cells

Jing Zhuang et al.

Summary: Regulating the electron transport layer (ETL) using the cost-effective modification material rubidium fluoride (RbF) can enhance the electron mobility of SnO2 and suppress hysteresis in perovskite solar cells (PSCs). Double-sided passivated PSCs with RbF on the SnO2 surface and p-methoxyphenethylammonium iodide on the perovskite surface achieved an outstanding PCE result with a small V-oc deficit.

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Tin Oxide Electron-Selective Layers for Efficient, Stable, and Scalable Perovskite Solar Cells

Cesur Altinkaya et al.

Summary: Tin oxide (SnO2) has emerged as a promising alternative to electron-selective layers (ESLs) in perovskite solar cells (PSCs), offering advantages such as high optical transmission, high carrier mobility, and low-temperature processability. It has the potential to play a key role in large-scale deployment and manufacturing.

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Solvent Engineering of the Precursor Solution toward Large-Area Production of Perovskite Solar Cells

Lingfeng Chao et al.

Summary: Solar cells based on emerging organic-inorganic hybrid perovskite materials have achieved impressive power conversion efficiency, but challenges remain in producing industrial-scale cells through solution methods. Advanced progress has been made in solvent engineering to regulate coordination and reduce toxicity of precursor solutions, showing promising prospects for future industrial production of high-performance cells.

ADVANCED MATERIALS (2021)

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Facilitating the formation of SnO2 film via hydroxyl groups for efficient perovskite solar cells

Yuchi Bai et al.

Summary: Interfacial engineering is an effective technique to enhance the photovoltaic performance of perovskite solar cells. By treating the surface of FTO glass and fabricating high-quality SnO2 film, the power conversion efficiency of PSCs can be improved. The optimized PSC demonstrates long-term stability and retains 97% of its initial PCE after a 4000-hour on-shelf lifetime test.

APPLIED SURFACE SCIENCE (2021)

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Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes

Hanul Min et al.

Summary: By introducing an interlayer between the electron-transporting and perovskite layers in perovskite solar cells, researchers have successfully enhanced charge extraction and transport from the perovskite, leading to higher power conversion efficiency and fewer interfacial defects. The coherent interlayer allowed the fabrication of devices with a certified efficiency of 25.5%, which maintained about 90% of its initial efficiency even after continuous light exposure for 500 hours. The findings provide guidelines for designing defect-minimizing interfaces in metal halide perovskites and electron-transporting layers.

NATURE (2021)

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Efficient perovskite solar cells via improved carrier management

Jason J. Yoo et al.

Summary: Metal halide perovskite solar cells have shown great potential to disrupt the silicon solar cell market with their improved performance, yet still face limitations in light-harvesting due to charge carrier recombination. Efforts to enhance charge carrier management offer a path to increase device performance and approach the theoretical efficiency limit of PSCs.

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Interpenetrating interfaces for efficient perovskite solar cells with high operational stability and mechanical robustness

Qingshun Dong et al.

Summary: This study introduces a new approach by incorporating an interpenetrating structure at the electron-transporting-layer interface in perovskite solar cells, enhancing their operational stability and mechanical robustness.

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Energy level engineering of charge selective contact and halide perovskite by modulating band offset: Mechanistic insights

Yassine Raoui et al.

Summary: Mixed cation and anion based perovskites solar cells show enhanced stability outdoors, but limited power conversion efficiency. Adjusting the electron band offset between the charge transport layers can improve performance.

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SnO2/TiO2 Electron Transporting Bilayers: A Route to Light Stable Perovskite Solar Cells

Mousa Abuhelaiqa et al.

Summary: Perovskite solar cells have driven a paradigm shift in photovoltaic research, but device stability remains a challenge. This study investigates the degradation at the ETL/perovskite interface, finding that SnO2 and TiO2/SnO2 ETLs show long-term stability compared to TiO2. SnO2 exhibits a passivation effect in the bilayered ETL configuration, suppressing charge recombination and enhancing optical durability.

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Interfacial toughening with self-assembled monolayers enhances perovskite solar cell reliability

Zhenghong Dai et al.

Summary: The use of iodine-terminated self-assembled monolayer (I-SAM) in perovskite solar cells (PSCs) leads to increased adhesion toughness at the interface, improved power conversion efficiency, reduced hysteresis, and enhanced operational stability. This is attributed to a decrease in hydroxyl groups at the interface and higher interfacial toughness achieved with I-SAM treatment.

SCIENCE (2021)

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Manipulating SnO2 Growth for Efficient Electron Transport in Perovskite Solar Cells

Zongyao Qian et al.

Summary: The addition of TiAcAc molecule to the SnO2 nanoparticle solution improves the electronic transport properties of SnO2 and enhances the efficiency of perovskite solar cells, while also increasing film uniformity and conductivity. Furthermore, the long alkene groups in TiAcAc act as stabilizers to prevent nanoparticle aggregation, demonstrating great potential for boosting the efficiency of perovskite solar cells.

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Antisolvent- and Annealing-Free Deposition for Highly Stable Efficient Perovskite Solar Cells via Modified ZnO

Ziyu Wang et al.

Summary: A complexed ZnO material (E-ZnO) was developed as an improved electron selective layer in perovskite solar cells, showing higher electron mobility and better energy level matching compared to traditional ZnO. By utilizing E-ZnO and a new perovskite film fabrication process without annealing or antisolvent, the highest efficiency of 20.39% was achieved for PSCs. Additionally, unencapsulated PSCs with E-ZnO maintained 95% of their initial efficiency after exposure to ambient atmosphere for 3604 hours.

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Interfacial Engineering via Self-Assembled Thiol Silane for High Efficiency and Stability Perovskite Solar Cells

Yunfan Shi et al.

Summary: This study demonstrates that using MPTMS SAM as an interlayer can effectively improve the performance of perovskite solar cells, increasing the power conversion efficiency and enhancing stability.

SOLAR RRL (2021)

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Laser-Scribing Optimization for Sprayed SnO2-Based Perovskite Solar Modules on Flexible Plastic Substrates

Babak Taheri et al.

Summary: The study introduces the combined concept of laser scribing optimization and automatized spray-coating of SnO2 layers for large-area FPSCs manufacturing. Results demonstrate that using spray-coating to deposit uniform compact SnO2 films on large-area plastic substrates can enable FPSCs to achieve high efficiency and scalability across different size scales.

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Multifunctional Conjugated Ligand Engineering for Stable and Efficient Perovskite Solar Cells

Ke Ma et al.

Summary: A novel multifunctional semiconducting organic ammonium cationic interface modifier is reported to boost the efficiency and stability of perovskite solar cells, achieving an excellent power conversion efficiency of 22.06%. By improving energy level alignment and stabilizing the interface, ion migration and halide phase segregation are suppressed, leading to long-term operational stability.

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Metal Oxide-Induced Instability and Its Mitigation in Halide Perovskite Solar Cells

Sampreetha Thampy et al.

Summary: Research highlights the importance of long-term stability in halide perovskite solar cells for practical applications. Interfacial interactions between transport layers and perovskite absorbers may lead to instability and impact device performance. Various degradation mechanisms and mitigation strategies have been discussed in order to achieve high-performing and stable PSCs.

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SnO2/ZnO as double electron transport layer for halide perovskite solar cells

Ubaid Khan et al.

Summary: By introducing a double electron transport layer (DETL), the energy loss in perovskite solar cells was effectively mitigated, resulting in an improved energy conversion efficiency of 15.22%. The best performance was achieved with an optimized thickness of ZnO layer reaching 210 nm.

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Up-Scalable Fabrication of SnO2 with Multifunctional Interface for High Performance Perovskite Solar Modules

Guoqing Tong et al.

Summary: By adding potassium permanganate in the chemical bath deposition process, high-quality large-area SnO2 films were successfully prepared, leading to enhanced performance of perovskite solar cells (PSCs). Utilizing a multifunctional interface engineering strategy, a power conversion efficiency (PCE) of 21.70% was achieved for lab-scale PSCs, with reduced hysteresis.

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Summary: Perovskite solar cells (PSCs) with SnO2 electron transporting layer (ETL) prepared using new methods demonstrate stronger charge extraction capabilities and achieve high performance. Research progress in SnO2 nanostructures and preparation methods, as well as passivation options like elemental doping, bilayer alterations, and interfacial modifications, can effectively enhance the efficiency of PSCs.

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KF-Doped SnO2 as an electron transport layer for efficient inorganic CsPbI2Br perovskite solar cells with enhanced open-circuit voltages

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Summary: KF-doped SnO2 is used as an ETL to enhance the performance of CsPbI2Br PVSCs, improving electron mobility and V-OC through regulation of the conduction band of SnO2 film and passivation of the interface with fluorine ions, resulting in increased V-OC and PCE of PVSCs.

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