Challenges and Perspectives of Organic Multivalent Metal-Ion Batteries

Rechargeable organic multivalent metal-ion batteries (MMIBs) have attracted a surge of interest as promising alternatives for large-scale energy storage applications because they can combine the advantages of both organic electrodes and multivalent metal-ion batteries. However, the development of organic MMIBs is hampered by many factors, which mean they lag far behind organic alkali-metal- (e.g., Li-, Na-, and K-) ion batteries. Herein, the challenges that are specifically faced by organic MMIBs are analyzed and the strategies that can probably solve such challenges are then discussed. As a special challenge that organic MMIBs are facing, the charge-storage mechanism is particularly underlined to deeply understand the structure-property relationships for guiding the future design of high-performance organic electrodes for MMIBs. The perspectives are thereby elaborated in this review with the outlook of practical applications of organic MMIBs.

Automated summary

This paper analyzes the challenges faced by organic multivalent metal-ion batteries (MMIBs) and discusses possible strategies to overcome them. The charge-storage mechanism is particularly emphasized to enhance the understanding of structure-property relationships for the design of high-performance organic electrodes for MMIBs. The practical applications of organic MMIBs are also explored in this review.