期刊
ADVANCED FUNCTIONAL MATERIALS
卷 32, 期 23, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202112598
关键词
high voltage; lithium metal batteries; non-flammable; ultralow-concentration electrolytes; wide temperature window
类别
资金
- National Natural Science Foundation of China [22179142, 22075314, 22075313]
- Science and Technology Project of Jiangxi Province [20192BCD40017]
- Outstanding Youth Fund of Jiangxi Province [20192BCB23028]
- Jiangxi Double Thousand Talent Program [JXSQ2019101072]
- Nano-X (Vacuum Interconnected Nanotech Workstation, Chinese Academy of Sciences, Suzhou)
This study successfully addresses the limitations of commercial carbonate electrolytes by fabricating a novel ultralow-concentration electrolyte with low cost, non-flammability, wide temperature operation window, and high electrochemical window. It also suppresses Li dendrite growth. The Li metal battery using this electrolyte shows outstanding performance under high voltage and wide temperature range.
High-voltage Li-metal batteries (LMBs) are regarded as next-generation high-energy-density storage devices to apply to extensive fields such as electric vehicles, space explorations, subsea operations, and grid-scale storages. Unfortunately, their practical applications are restricted by some defects of commercial carbonate electrolytes including flammability, low oxidation stability, narrow temperature operation window, and Li dendrites growth. Herein, a novel ultralow-concentration electrolyte (ULCE, 0.1 m) is fabricated by dissolving lithium difluoro(oxalato)borate in N-methyl-N-methoxyethyl-pyrrolidinium bis(trifluoromethylsulfonyl)imide ([MEMP][TFSI]) ionic liquid and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether. This advanced ULCE exhibits impressive merits including low cost, non-flammability, wide operation temperature (-100 to +70 degrees C), and high electrochemical window (5.75 V). Meanwhile, it helps to suppress Li dendrite growth due to the combined effect of the cation shielding by MEMP+ cations and robust solid electrolyte interphase formed by the preferential decomposition of DFOB- and TFSI- anions. The LiNi0.6Co0.2Mn0.2O2 (NCM622)/Li cell with ULCE shows outstanding performance under a high voltage of 4.5 V and a wide temperature range from -60 to 70 degrees C. This work provides a distinctive sight to design advanced electrolyte for lower cost, safe, and wide-temperature high-energy-density LMBs.
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