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Article
Chemistry, Multidisciplinary
Kefeng Ouyang et al.
Summary: A strategy to build an indium metal interphase on the zinc anode surface is proposed, preventing hydrogen evolution reaction and zinc corrosion, guiding smooth zinc deposition. This approach achieves ultrahigh cumulative capacities and stable plating/stripping behavior, with encouraging rate performance and cyclic stability for Zn-V2O5 batteries.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zhikun Guo et al.
Summary: The zinc-ion battery is gaining attention for its safety and environmental benefits, but dendrite formation and dead zinc accumulation can reduce battery life. A self-adaptable PDMS/TiO2-x coating has been developed to address these issues, inhibiting dendrite growth and maintaining stability during cycling. The cells achieved a high coulombic efficiency after 700 cycles, showcasing the effectiveness of the adaptive interface coating.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Yizhou Wang et al.
Summary: A novel strategy is proposed in this study to prevent zinc dendrite growth in aqueous zinc-ion batteries by using a selectively polarized ferroelectric polymer material as a protective layer on the zinc anodes. This approach enables long cycling lifespan and high rate performance of the batteries. The work provides insight into protecting zinc anodes and potentially other metal anodes using polymer ferroelectricity.
ADVANCED MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Shiyin Xie et al.
Summary: This article reports a novel strategy of using zincophilic Cu nanowire networks to stabilize zinc anodes. The Cu nanowire networks can homogenize the surface electric field and Zn2+ concentration field, and inhibit side reactions through their hydrophobic feature. The facets and edge sites of the Cu nanowires, especially the latter ones, are highly zincophilic, which promotes uniform zinc nucleation/deposition. The protected zinc anodes exhibit an ultralong cycle life and rapid charge/discharge ability.
NANO-MICRO LETTERS
(2022)
Article
Nanoscience & Nanotechnology
Ji Young Kim et al.
Summary: This study presents a limitedly Zn-doped MgF2 interphase on the surface of Zn metal electrodes to address issues such as hydrogen evolution reaction and dendrite formation. The interphase structure reduces the interfacial resistance and enables fast kinetics and uniform deposition of Zn ions, leading to improved battery performance.
NANO-MICRO LETTERS
(2022)
Review
Chemistry, Physical
Ahmad Naveed et al.
Summary: Zinc batteries are praised for their safety, environmental friendliness, and low toxicity, but the poor rechargeability of the zinc anode hinders their applications. By studying the zinc electrochemistry in different electrolyte systems and suggesting methods to improve the reversibility and stability of the zinc anode, the potential of organic electrolytes with safe organic solvents for high-performance zinc ion batteries is highlighted.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Miao He et al.
Summary: The introduction of a multi-functional interface layer based on ZIF can effectively inhibit parasitic reactions and dendritic growth, improve cation transfer efficiency, and reduce the impact of water molecules in the electrolyte.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Applied
Ming Yang et al.
Summary: In this work, a C@VO2 composite was constructed via anti-aggregation growth and hierarchical porous carbon encapsulation to improve the electrochemical performance of aqueous zinc-ion batteries (AZIBs). The morphology and pore structure of the composite can be regulated by tuning the adding amount of glucose. The C@VO2-3:3 composite delivered a high capacity of 281 mAh g-1 at 0.2 A g-1 as a cathode for AZIBs, and exhibited remarkable rate capability and cyclic stability. The evolution of crystal structure, valence state, and transport kinetics upon cycling was also investigated. The synergistic effect of anti-aggregation morphology and hierarchical porous carbon encapsulation in the C@VO2 composite enhances the ion accessible site and transport kinetics, resulting in superior storage performance. This design concept can be applied to other types of electrode materials, accelerating the development of high-performance AZIBs.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Chemistry, Physical
Rui Li et al.
Summary: In this study, a concentric-ring like additive, 18C6, was used to capture Zn ions on the surface through confinement effects during the electrochemical process, resulting in decelerated Zn deposition and reduced by-product yield. The cycling performance of Zn symmetric cells was significantly improved.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Xianzhong Yang et al.
Summary: The study successfully inhibited Zn dendrite formation and side reactions by depositing a ZnSe film on commercial Zn foil, leading to improved cyclic stability of the battery and providing feasibility for commercial applications.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Physical
Zhehan Yi et al.
Summary: Zinc-ion batteries are considered promising candidates for next-generation energy storage systems due to their high safety, resource availability, and environmental friendliness. However, the instability of the Zn metal anode has hindered their reliable deployment, and efforts have been made to overcome this through electrode structure design, interface modification, and electrolyte/separator optimization. Understanding and categorizing these strategies based on their intrinsic mechanisms are important for the development of novel Zn metal anodes for ZIBs.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Fangxi Xie et al.
Summary: The bonding between zinc ions and zincophilic sites is revealed as the mechanism for suppressing zinc-dendrite formation in the ZMA host, leading to enhanced electrochemical performance. This study highlights the importance of nitrogen zincophilic sites in inhibiting zinc-dendrite growth.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Weijun Zhou et al.
Summary: Low-cost sodium lignosulfonate was used as an electrolyte additive to improve the cyclability of rechargeable zinc-ion batteries, resulting in enhanced capacity retention and cycle life.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Minfeng Chen et al.
Summary: A all-round hydrogel electrolyte was developed using cotton, tetraethyl orthosilicate, and glycerol, exhibiting high ionic conductivity and excellent mechanical properties.
ADVANCED MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Kai Wu et al.
Summary: The research suggests that the engineered BaTiO3 artificial solid-electrolyte interface helps regulate zinc deposition, leading to even zinc stripping/plating and limited zinc dendrite growth. This technology not only enhances the cycling stability of the battery, but also achieves nearly 100% Coulombic efficiency at 2 A g(-1).
NANO-MICRO LETTERS
(2021)
Article
Nanoscience & Nanotechnology
Ziqi Wang et al.
Summary: This study presents a Janus separator based on a Zn-ion conductive metal-organic framework (MOF) and reduced graphene oxide (rGO), which can simultaneously regulate uniform Zn2+ flux and electron conduction during battery operation, effectively improving the stability and corrosion issues of Zn anodes.
NANO-MICRO LETTERS
(2021)
Article
Multidisciplinary Sciences
Yao Shan et al.
Summary: The authors demonstrate a gravity-driven sintering strategy for fabricating complex piezoceramics, offering potential for the production of electromechanical devices with unique geometries.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Long Zhang et al.
Summary: The introduction of a multifunctional ZnSe protective layer effectively addresses the corrosion, hydrogen evolution, and dendrite formation issues in aqueous Zn metal batteries, improving the stability and performance of the batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Rui Li et al.
Summary: This study introduces a tin oxide/barium titanate heterostructure encapsulated in nitrogen-doped carbon nanofibers as a sodium ion battery anode, and utilizes the ferroelectric and piezoelectric effect to boost the rate performance of the anode.
Article
Chemistry, Multidisciplinary
Xia Wang et al.
Summary: Acid etching can improve the electrodeposition quality and corrosion resistance of zinc metal anodes, enhancing Zn2+ ion kinetics; phosphoric acid etching yields the most compact layer; the zinc phosphate@Zn electrode shows stable cycling and fast kinetics in zinc metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Canbin Deng et al.
Summary: The surface of the Zn metal anode is reconstructed by a cerium-based conversion film (Zn@CCF), effectively preventing rapid growth of the film near zinc grain boundaries, resulting in long lifespan and low polarization power. This research helps suppress zinc dendrite formation and underscores the importance of surface reconstruction of the Zn metal anode for corrosion inhibition.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Qinghe Cao et al.
Summary: The proposed 3D nitrogen-doped vertical graphene nanosheets grown on carbon cloth improve the performance of zinc-ion batteries by achieving uniform zinc nucleation, optimizing electric distribution, and enhancing the zinc deposition/stripping process, leading to higher electrochemical performance. This technology not only achieves high cycling stability of the battery, but also exhibits outstanding mechanical flexibility, showing great potential for portable and wearable electronics.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Peng Sun et al.
Summary: The addition of glucose in ZnSO4 electrolyte can improve the performance of Zn ion batteries by suppressing Zn dendrite growth and side reactions, enhancing stability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Engineering, Environmental
Yongchang Liang et al.
Summary: A unique interface strategy, utilizing N,O co-doped Carbon nanofiber (CNF) interlayers on Zn metal anode surface, has been reported to regulate electrodeposition kinetics and inhibit dendrite formation in Aqueous zinc-ion batteries (AZIBs). The modified cell showed high Zn plating/stripping reversibility and stability at high current density, providing a new route to enable dendrite-free Zn metal anodes and high-performance AZIBs.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Multidisciplinary Sciences
Zhen Hou et al.
Summary: The study successfully achieved dendrite-free zinc morphologies and superior cycling stability under high current densities and large cycling capacities by regulating the separator's interfacial chemistry through tin coating. This approach suppressed dendrite initiation and ensured smooth zinc metal deposition, offering a promising route to overcome challenges associated with metal anodes.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Sung Hyun Park et al.
Summary: The study successfully stabilized zinc (Zn) metal anodes by building a thin and hydrophilic artificial solid electrolyte interphase (SEI) layer, which effectively inhibits parasitic side reactions and zinc dendrite growth, achieving durable cycle stability and showing promise for developing large-scale aqueous zinc-ion batteries (ZIBs).
ACS ENERGY LETTERS
(2021)
Article
Chemistry, Physical
Yongtai Xu et al.
Summary: The article introduces a new type of zinc/sodium manganese oxides battery, which improves structure by pre-inserting Na+ ions and crystal water in the cathode interlayer, and eliminates zinc dendrites by adding Na2SO4 in the electrolyte, achieving high capacity and long-term cyclic stability.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Xinhua Zheng et al.
Summary: This review focuses on the problems and solutions in the Zn electrodeposition process in rechargeable zinc-ion batteries (ZIBs), aiming to provide practical strategies for the future development of stable ZIBs.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Yongling An et al.
Summary: By designing and constructing a protective heterogeneous layer composed of sulfur-doped three-dimensional (3D) MXene and ionic conductive ZnS on the zinc anode, the issues of dendrite growth and side reactions hindering the practical applications of zinc anode in aqueous batteries have been successfully addressed. This results in a stable and dendrite-free zinc anode with notable cycling stability and high-rate performance.
Article
Chemistry, Multidisciplinary
Yuzhu Chu et al.
Summary: The in situ construction of a composite SEI mainly composed of Zn-3(PO4)(2) and ZnF2 (ZCS) effectively suppresses Zn dendrite growth and accelerates Zn2+ transference and deposition kinetics in aqueous Zn-ion batteries. By taking advantage of the instability of KPF6 in an aqueous environment, an in situ ZCS is successfully built on the Zn anode through a PF6- anion-induced chemical strategy, showing enhanced reversibility and excellent electrochemical performance. This work not only paves a new way for designing a desirable SEI on the Zn anode, but also may guide the interface engineering of other systems to overcome intrinsic defects in constructing favorable interphases.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Xiaotan Zhang et al.
Summary: The CNG membrane, serving as a desolvation layer, effectively prevents water molecules from contacting the zinc anode, thereby delaying water-induced corrosion reactions and promoting redirected zinc deposition through deanionization shock. The flexible and toughened nature of the CNG membrane allows it to withstand strong forces and accommodate surface fluctuations of the zinc anode during plating/stripping processes, resulting in enhanced Coulombic efficiency and extended cycle life.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Chemistry, Physical
Hai-Yang Wu et al.
Summary: In this work, a stable electrolyte additive, a classic Anderson-type polyoxometalate, was employed to suppress zinc dendrite growth during Zn plating/stripping, resulting in significantly improved cycle life of Zn anodes in symmetric cells and high capacity retention in Zn/NVO full cells. The utilization of ultra-stable polyoxometalate additives with strong complexation with metal ions provides researchers with a new conception for constructing long-term cycling life aqueous rechargeable batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Ming Yang et al.
Summary: This study presents a rational design of holey carbon-encapsulated vanadium dioxide nanobelts as cathode material for high-performance aqueous Zn-ion batteries (AZIBs) via a unique dual-engineering strategy. The electrode shows excellent capacity and high-rate performance, with stable electron transport process confirmed by in situ electrochemical impedance spectra. The systematic studies of the reaction mechanism provide scientific guidance for designing other advanced cathodes and contribute to a deep understanding of the fundamentals of AZIBs.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
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Yanbin Yin et al.
ADVANCED MATERIALS
(2020)
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Canbin Deng et al.
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(2020)
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Sheng-Bo Wang et al.
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(2020)
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(2020)
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Junnan Hao et al.
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(2020)
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Jian Zhi et al.
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Jiaofu Li et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Review
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Ziyi Cao et al.
ADVANCED ENERGY MATERIALS
(2020)
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Yao Qin et al.
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Bo Yong et al.
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(2020)
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Qi Yang et al.
ADVANCED MATERIALS
(2020)
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(2020)
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Jin Cao et al.
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(2020)
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Xuesong Xie et al.
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(2020)
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(2019)
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Yinxiang Zeng et al.
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(2019)
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Vladimir Yufit et al.
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Litao Kang et al.
ADVANCED ENERGY MATERIALS
(2018)
Review
Chemistry, Physical
Guozhao Fang et al.
ACS ENERGY LETTERS
(2018)
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Keyu Xie et al.
ADVANCED MATERIALS
(2017)
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Enrico Andreoli et al.
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
(2012)
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Juan G. Castano et al.
JOURNAL OF MATERIALS SCIENCE
(2007)
