期刊
ACTA MATERIALIA
卷 229, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.actamat.2022.117844
关键词
Structure; Transmission electron microscopy; Vacancies; Phase transformation; Electrical conductivity
资金
- National Key Research and Development Program of China [2017YFA0700701]
- Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science [2019JH3/30100020]
- National Natural Science Foun-dation of China [91960202, 52171020, 51901229]
- Institute of Metal Research Chinese Academy of Sciences [552021-PY07]
Phase engineering of nanomaterials is gaining increasing research interest due to the influence of crystal structures on the physical and chemical properties of metals. In this study, a novel simple hexagonal structured gold was fabricated through in situ selective etching on an ordered Cu-Au intermetallic compound, demonstrating a low coordination number and packing fraction. The discovery of this new crystal structure suggests that metals can form diverse structures by changing their effective atomic volume, providing opportunities for engineering new physical properties and applications.
Phase engineering of nanomaterials attracts increasing research interest, as crystal structures of metals often determine their physical and chemical properties. Metals tend to form close-packed crystal structures to maximize their space filling and atomic coordination numbers due to the isotropic metallic bonding. Hitherto no metals yet crystallize with the simple hexagonal packing which has low coordination number and packing fraction. Here, we fabricate a novel simple hexagonal structured gold through in situ selective etching on ordered Cu-Au intermetallic compound, where the new crystal structure has only 8 nearest neighbors for each atom and a low packing fraction of 0.60. The simple hexagonal structured Au demonstrates an electrical conductivity of 389 S/m, approximately 10(5) times lower than that of face centered cubic structured gold, according to first principles calculation, associated with localized valence electrons. The discovery of simple hexagonal structure suggests that metals can form more diverse crystal structures by changing effective atomic volume, which provides a pathway to engineer new structures of metals for novel physical properties and applications. (C) 2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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