Two-Dimensional Superconductivity of Ca-Intercalated Graphene on SiC: Vital Role of the Interface between Monolayer Graphene and the Substrate

Ca-intercalation has enabled superconductivity in graphene on SiC. However, the atomic and electronic structures that are critical for superconductivity are still under discussion. We find an essential role of the interface between monolayer graphene and the SiC substrate for superconductivity. In the Ca-intercalation process, at the interface a carbon layer terminating SiC changes to graphene by Ca-termination of SiC (monolayer graphene becomes a bilayer), inducing more electrons than a free-standing model. Then, Ca is intercalated in between the graphene layers, which shows superconductivity with the updated critical temperature (T-C) of up to 5.7 K. In addition, the relation between T-C and the normal-state conductivity is unusual, dome-shaped. These findings are beyond the simple C6CaC6 model in which s-wave BCS superconductivity is theoretically predicted. This work proposes a general picture of the intercalation-induced superconductivity in graphene on SiC and indicates the potential for superconductivity induced by other intercalants.

Automated summary

This study reveals the crucial role of the interface between monolayer graphene and the SiC substrate in the superconductivity induced by Ca-intercalation. Through Ca-termination of SiC, the carbon layer at the interface changes to graphene, and Ca is intercalated between the graphene layers, leading to superconductivity. The relationship between the critical temperature and the normal-state conductivity exhibits an unusual dome-shaped pattern.