Greatness in Simplicity: Efficient Red Room-Temperature Phosphorescence from Simple Halogenated Maleimides with a 2D Layered Structure

Herein, two maleimide derivatives substituted by Br (DBM) and I (DIM) with a two-dimensional (2D) layered structure are found to have highly efficient red room-temperature phosphorescence (RTP) at 660 nm in solid state, which is independent of their morphology (crystal, powder, and film). The red RTP of DBM and DIM is closely related to the synergism of n(pi)-ct-pi* transitions and the 2D halogen-bonded network. Interestingly, the red RTP can be excited by visible light of 500 nm, which should be ascribed to the forbidden absorption from the ground state to the triplet state activated in the layered halogen-bonded framework. Due to the rich intermolecular interactions in the rigid layered structure, the red RTP of DBM is very stable under water or external force stimulation. Notably, Hg(II) and Cd(II) ions in a pure aqueous solution result in an opposite change in the RTP intensity of the DBM film. The detection limit of Hg(II) ion is as low as 2.5 X 10(-5) nM, lesser than all reported values. The above results not only provide a new idea for the design of simple and efficient red RTP materials but also make it possible to develop solid-state phosphorescent probes for toxic heavy metal ions in environmental sewage with high sensitivity and selectivity.

Automated summary

In this study, two maleimide derivatives with a two-dimensional layered structure exhibited highly efficient red room-temperature phosphorescence (RTP) in solid state. The red RTP was attributed to the synergism of n(pi)-ct-pi* transitions and the 2D halogen-bonded network. Interestingly, the red RTP could be excited by visible light at 500 nm and remained stable under water or external force stimulation. Furthermore, these materials showed high sensitivity and selectivity in detecting toxic heavy metal ions in environmental sewage.