期刊
ACS APPLIED MATERIALS & INTERFACES
卷 14, 期 17, 页码 19623-19628出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c04746
关键词
hydrogen-bonded organic framework; microporous materials; gas separation; xenon capture; krypton
资金
- National Natural Science Foundation of China [21975044, 21971038, 21978254, 21922810]
- Fujian Provincial Department of Science and Technology [2019H6012, 21019L3004]
- Welch Foundation [AX-1730]
In this study, a novel ultramicroporous hydrogen-bonded organic framework (HOF-40) constructed from a cyano-based organic building unit was reported. The results showed that HOF-40 exhibited superior separation performance for xenon/krypton mixtures, and the pore confinement effect and abundant accessible binding sites played a synergistic role in this challenging gas separation.
Separation of xenon/krypton gas mixtures is one of the valuable but challenging processes in the gas industries due to their close molecular size and similar physical properties. Here, we report a novel ultramicroporous hydrogen-bonded organic framework (termed as HOF-40) constructed from a cyano-based organic building unit of 1,2,4,5-tetrakis(4-cyanophenyObenzene (TCPB), exhibiting superior separation performance for Xe/Kr mixtures, as clearly demonstrated by dynamic breakthrough curves. GCMC simulation results indicate that the pore confinement effect and abundant accessible binding sites play a synergistic role in this challenging gas separation. Furthermore, this cyano-based HOF displays excellent chemical stability from 12 M HCl to 20 M NaOH aqueous solutions.
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