期刊
CCS CHEMISTRY
卷 3, 期 11, 页码 2764-2771出版社
CHINESE CHEMICAL SOC
DOI: 10.31635/ccschem.020.202000588
关键词
amides; visible light; carbene; photocascade; rearrangement
资金
- National Natural Science Foundation of China [21971001, 21702001]
- Anhui University
A green and sustainable synthetic strategy for amide bond formation using visible light as the sole energy source was developed, with nitrones generated in situ and nitrogen gas produced as the only byproduct. This method has potential applications in the synthesis of amides containing important natural products and drug-based complex molecules.
A green and sustainable synthetic strategy for amide bond formation utilizing a visible light-promoted nitrone formation/rearrangement cascade was developed. This method utilized visible light as the sole and clean energy source without the need for an exogenous photoredox catalyst or additive. Moreover, nitrones are generated in situ, bypassing the isolation process and producing only nitrogen gas as a byproduct. The synthetic value of this protocol has potential applications in the syntheses of amides containing important natural products and drug-based complex molecules. [GRAPHICS] .
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