4.6 Article

Diffusion behavior and distribution regulation of MgO in MgO-bearing pellets

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SPRINGER
DOI: 10.1007/s12613-016-1318-9

关键词

magnesia; iron oxide; ore pellets; diffusion; distribution

资金

  1. China Postdoctoral Science Foundation [2016M591445]
  2. Postdoctoral Science Foundation of NEU China [20160302]
  3. National Natural Science Foundation of China [51604069]

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In this paper, the diffusion behavior between MgO and Fe2O3 (the main iron oxide in pellets) is investigated using a diffusion couple method. In addition, the distribution regulation of MgO in MgO-bearing pellets is analyzed via pelletizing experiments. The results illustrate that MgO is prone to diffuse into Fe2O3 in the form of solid solution; the diffusion rate considered here is 13.64 A mu m center dot min(-1). Most MgO content distributes in the iron phase instead of the slag phase. The MF phase {(Mg1-x Fe-x)O center dot Fe2O3, x aecurrency sign 1} is generated in the MgO-bearing pellets. However, the distribution of MgO in the radial direction of the pellets is inconsistent. The solid solution portion of MgO in the MF phase is larger in the outer layer of the pellets than in the inner layer. In this work, the approximate chemical composition of the MF phase in the outer layer of the pellets is {(Mg0.35-0.77 center dot Fe0.65-0.23) O center dot Fe2O3} and in the inner layer is {(Mg0.13-0.45 center dot Fe0.87-0.55) O center dot Fe2O3}.

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