Heterogeneous advanced oxidation processes over stoichiometric ABO3 perovskite nanostructures

The interest on single, stoichiometric ABO(3) perovskites for heterogeneous advanced oxidation processes (AOPs) has grown in recent years because of their remarkable catalytic properties and versatile applicability. This review is devoted to highlighting and discussing the most recent developments and applications of ABO(3) perovskites and their derived nanocomposites in water treatment and disinfection via AOPs. A brief overview of perovskites, with emphasis on ABO(3) materials, their synthesis strategies, structure and properties, has been presented. More significant, the recent applications of ABO(3) materials in photocatalysis, Fenton/photo-Fenton, persulphate activation, sonocatalysis/sonophotocatalysis, catalytic/photocatalytic ozonation, piezocatalysis/piezo photocatalysis and photoelectrocatalytic oxidation, has been well reviewed. Specifically, the catalytic activity of the ABO(3) perovskites could be modulated through selection of the synthesis protocol and controlling the synthesis conditions, doping and co doping of metal and non-metal ions, incorporation of carbon nanomaterials and heterojunction formation with other semiconducting materials. Furthermore, the use of ABO(3) materials in conjunction with oxidants such as persulphate, H2O2 and O-3 yielded boosted activity of the hybrid processes compared with single processes. Details on the mechanisms of the charge carriers' formation and transfer in the different ABO(3-)mediated AOPs have been discussed to enhance the understanding of the degradation mechanism. Finally, some concluding remarks and outlook are detailed in terms of the general pitfalls and how they can be mitigated to provide guidance for future research and improve the exploitation of ABO3 perovskites in water treatment and environmental remediation applications.(c) 2022 Elsevier Ltd. All rights reserved.

Automated summary

In recent years, ABO(3) perovskite materials have been widely used in heterogeneous advanced oxidation processes (AOPs) for water treatment and disinfection due to their remarkable catalytic properties. This review provides an overview of the synthesis strategies, structure, and properties of ABO(3) materials, and discusses their recent applications in various AOPs, including photocatalysis, Fenton/photo-Fenton, persulphate activation, sonocatalysis/sonophotocatalysis, catalytic/photocatalytic ozonation, piezocatalysis/piezo photocatalysis, and photoelectrocatalytic oxidation. The catalytic activity of ABO(3) perovskites can be modulated through synthesis protocol, doping, heterojunction formation, and the incorporation of carbon nanomaterials. Moreover, the combination of ABO(3) materials with oxidants such as persulphate, H2O2, and O-3 enhances the activity of hybrid processes. The review also discusses the mechanisms of charge carriers' formation and transfer in ABO(3-)mediated AOPs.