期刊
ACS APPLIED POLYMER MATERIALS
卷 3, 期 12, 页码 6326-6337出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsapm.1c01093
关键词
PEO/PLA blends; single-ion polymer electrolyte; lithium battery; dual-ion polymer electrolyte; high-temperature batteries
资金
- Consejo Nacional de Ciencia y Tecnologia (National Council of Science and Technology) (CONACyT), Mexico [471837]
- Secretaria de Educacion, Ciencia, Tecnologia e Innovacion from Ciudad de Mexico [SECTEI/133/2019]
- Basque Government [IT1309-19]
This article investigates the blending strategy of PEO with PLA in solid-state lithium batteries to extend their use at high temperatures (100 degrees C). The addition of PLA enhances the mechanical properties of the electrolytes and leads to higher ionic conductivities at elevated temperatures.
Lithium batteries are in high demand in different technological fields. However, the operating temperature is required to be below 70 degrees C, and this limits their use in applications demanding high-energy rechargeable batteries that are able to operate at temperatures above 100 degrees C. Poly(ethylene oxide) (PEO) is, currently, the reference solid polymer electrolyte (SPE) employed in solid-state lithium batteries. However, the application of PEO at higher temperatures is restricted due to the loss of mechanical properties. In this article, we show that the polymer blending strategy of blending PEO with poly(L,L-lactide) (PLA) allows extending its use in batteries at high temperatures (100 degrees C). This improvement is due to the mechanical reinforcement of PEO solid electrolytes associated with the presence of PLA crystals. Thus, two solid electrolyte systems based on PEO/PLA blends with either a LiTFSI salt or a lithium single-ion polymer (poly(lithium-1-[3-(methacryloyloxy)propylsulfonyl]-1-(trifluoromethanesulfonyl) imide), PLiMTFSI) were investigated and compared. Differential scanning calorimetry (DSC) results indicate that regardless of the concentration of LiTFSI or PLiMTFSI in the blend, crystals of PLA are present with melting peaks at 160-170 degrees C and the lithium salt distributes preferentially in the PEO-rich amorphous phases. The ionic conductivity is negatively affected by the incorporation of PLA in the blends. However, at high temperatures (>70 degrees C), ionic conductivities of similar to 10(-4) S cm(-1) were obtained for both systems. DMTA results showed that PLA addition increases the mechanical properties of the electrolytes, yielding storage modulus values of similar to 10(6) Pa for the PEO/PLA/LiTFSI blend and similar to 10(7) Pa or higher for the PEO/PLA/PLiMTFSI blend at high temperatures (100 degrees C). Finally, both ternary blends were compared in a symmetrical lithium battery at 100 degrees C, and the single-ion conducting PEO/PLA/PLiMTFSI system presented lower overpotentials, which is reflected in a lower polarization inside the lithium battery.
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