期刊
ACS APPLIED POLYMER MATERIALS
卷 4, 期 3, 页码 1551-1558出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsapm.1c01554
关键词
polydimethylsiloxane; thermoplastic polyurethanes; microphase separation; cold resistance; toughness; high flexibility
资金
- National Science Foundation for Young Scientists of China [52003016]
- Fundamental Research Funds for the Central Universities [buctrc202117]
A series of PDMS-based thermoplastic polyurethanes (TPUs) with excellent cold resistance and toughness were synthesized. The PDMS-based TPU exhibited a maximum tensile strength of 18.46 MPa and a maximum coefficient of cold resistance of 0.704 at -50 degrees C, making it a promising material for 3D printing in low temperature environments.
In order to fabricate a tough material with excellent cold resistance, we designed a series of polydimethylsiloxane (PDMS)-based thermoplastic polyurethanes (TPUs). Bis[(3-(2-hydroxyethoxy)propyl)dimethylsilyl]-terminated PDMS was chosen as a soft segment to interact with a hard segment consisting of dicyclohexylmethane-4,4'-diisocyanate and 1,4-butanediol. By combination of the advantages of PDMS and TPU, the maximum tensile strength of the synthesized PDMS-based TPU reached 18.46 MPa, and the maximum coefficient of cold resistance under compression at -50 degrees C was 0.704, which is higher than that of traditional cold-resistant rubbers. Remarkably, the prepared PDMS-based TPU is tough enough to function properly at lower temperature as a 3D-printing material and can be utilized in various applications.
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