Effect of Al and Mg Doping on Reducing Gases Detection of ZnO Nanoparticles

In this work, the main objective is to enhance the gas sensing capability through investigating the effect of Al and Mg doping on ZnO based sensors. ZnO, Mg-1% doped ZnO, Al-5% doped ZnO and (Al-5%,Al- Mg-1%) co-doped ZnO nanoparticles (NPs) were synthesized by a modified sol-gel method. The structural characterization showed the hexagonal crystalline structure of the prepared samples. Morphological characterizations confirmed the nanometric sizes of the NPs (27-57 nm) and elemental composition investigation proved the existence of Al and Mg with low concentrations. The optical characterization showed the high absorbance of the synthesized samples in the UV range. The gas sensing performances of the synthesized samples, prepared in the form of thick films, were investigated. Sensing tests demonstrated the high influence of the Al and Mg on the sensing performances towards H-2 and CO gas, respectively. The 5A1MZO-based sensor exhibits high sensitivity and low detection limits to H-2 (< 2 ppm) and CO (< 1 ppm). It showed a response around 70 (at 250 & DEG;C) towards 2000 ppm H-2 and 2 (at 250 & DEG;C) towards CO.

Automated summary

The study aims to enhance the gas sensing capability of ZnO based sensors through investigating the effect of Al and Mg doping. Experimental results show that Al and Mg have a significant impact on the sensing performances towards H-2 and CO gases. The sensor based on 5A1MZO exhibits high sensitivity and low detection limits to H-2 and CO.