4.7 Article

Interlayer-expanded MoS2 hybrid nanospheres with superior zinc storage behavior

期刊

COMPOSITES COMMUNICATIONS
卷 27, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.coco.2021.100841

关键词

Zn ion batteries; MoS2-O Composites; Cathode materials; Structural stability

资金

  1. National Natural Science Foundation of China [51703208]
  2. Fundamental Research Funds for the Central Universities [JUSRP22040]
  3. Natural Science Foundation of Jiangsu Province, China [BK20190613]

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The study successfully synthesized a highly stable MoS2-O nanosphere with intercalated Mo-O bonds as a cathode material for Zn ion batteries. The sulfidation degree expanded the interlayer spacing of MoS2, while the intercalated Mo-O bonds enhanced the structural integrity and stability of the fabricated cathode during Zn insertion/extraction cycles. This optimized structure significantly improved the specific capacity and cycling stability of ZIBs with MoS2-O nanosphere cathode over 300 cycles, showing promise for enhancing the capacity retention performance of MoS2 in ZIBs.
As a promising cathode candidate, molybdenum disulfide (MoS2) has attracted extensive attention due to its excellent layered structure for Zn ion storage. However, the poor specific capacity and the relatively short cycling lifespan remain a challenge to fulfilling its potential applications. Herein, we successfully synthesized a highly stable MoS2-O nanosphere with intercalated Mo-O bonds adjacent to the MoS2 layers as cathode material for Zn ion batteries (ZIBs). The results demonstrate that the degree of sulfidation contributed to the expansion of the interlayer spacing of MoS2 while the intercalated Mo-O bonds aided the structural integrity and the stability of the fabricated cathode during the repeated Zn insertion/extraction process. Due to the optimized structure, the specific capacity and cycling stability of ZIBs with MoS2-O nanosphere cathode improved significantly over 300 cycling with an initial specific capacity of 206.7 mAh.g(-1) at 100 mA g(-1). This work provides a promising approach to effectively enhance the capacity retention performance of MoS2 for ZIBs.

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