4.6 Review

Quaternary nitrogen redox centers for battery materials

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出版社

ELSEVIER
DOI: 10.1016/j.coelec.2021.100745

关键词

Quaternary nitrogen; Redox center; Organic batteries; Electrical energy storage

资金

  1. National Natural Sci-ence Foundation of China [51772199]
  2. Natural Science Foundation of the Jiangsu Higher Education Institutions of China [20KJB480002]
  3. Collaborative Innovation Center of Suzhou Nano Science Technology

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This review presents recent advances in the use of redox-active organics with quaternary nitrogen redox centers as electrode materials for batteries, focusing on molecular design. Challenges and potential solutions for the application of organic materials in battery cathodes are also discussed from the perspective of cell chemistry.
Rechargeable batteries using redox-active organics as the electrode material have been proposed to be a promising alternative to lessen the reliance on unrenewable resources and to broaden the chemistry of current battery technology. However, organic materials, particularly for the battery cathode, are encountered with unsatisfactory stability and relatively low redox potential compared with the inorganic counterparts. This review introduces some recent advances of redox-active organics based on quaternary nitrogen redox centers with a focus on molecular design. The challenges and possible solutions are also introduced from the perspective of cell chemistry.

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