期刊
MATERIALS CHEMISTRY FRONTIERS
卷 6, 期 1, 页码 24-32出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qm01280k
关键词
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资金
- JSPS KAKENHI [17H03112, 21H01995]
- China Scholarship Council (CSC)
- Grants-in-Aid for Scientific Research [17H03112, 21H01995] Funding Source: KAKEN
A novel imide compound and polyimides with multiple intramolecular hydrogen bonds were synthesised to investigate the effects of distinct H-bond structures on photoluminescence properties, revealing excited-state intramolecular proton transfer as the main luminescence mechanism. These compounds show promise for solar spectral conversion applications.
A novel imide compound (DH-MC) and polyimides (DH-PIs) that form multiple intramolecular hydrogen bonds (H-bonds) were synthesised from 2,2 '-dihydroxybenzophenone-3,3 ',4,4 '-tetracarboxylic dianhydride (DHBA) to investigate the effects of distinct H-bond structures on the photoluminescence properties of these compounds. The DHBA moiety, which contains two proton donors and three proton acceptors, can form three types of H-bond structures (MC-0, MC-1, and MC-2). DFT calculations have predicted that the most energetically stable conformation is MC-1, forming an asymmetric H-bond structure, which is consistent with the FT-IR spectroscopy and single-crystal XRD analysis results. A colourless toluene solution of DH-MC exhibited orange fluorescence with a large Stokes shift (nu = 11 905 cm(-1)), and DH-MC and the DH-PIs exhibited yellow fluorescence with a large nu of >10 000 cm(-1) in the solid state, with both originating from excited-state intramolecular proton transfer (ESIPT). In addition, these compounds exhibit small-Stokes-shifted fluorescence from the anionic form of the DHBA moiety, resulting in yellow coloration of the DH-PI film and the DH-MC powder. To reduce coloration, a polyimide copolymer (CoPI) film was prepared using DHBA and 4,4 '-oxydiphthalic anhydride (ODPA) in which the molar ratio of DHBA was set at 3%. Owing to the dilution effect and efficient energy transfer from the blue-fluorescent ODPA to the DHBA moiety in the excited state, the colourless and transparent CoPI film exhibited prominent yellow fluorescence with a quantum yield of 0.14. The wavelength-converting spectrum demonstrated that the CoPI film absorbs a wide range of UV radiation from a xenon light source and significantly enhances the yellowish light component via ESIPT emission. The CoPI film is a promising candidate for solar spectral conversion applications.
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