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Advances and Potentials of NiOx Surface Treatments for p-i-n Perovskite Solar Cells

期刊

SOLAR RRL
卷 6, 期 3, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/solr.202100700

关键词

nickel oxide (NiOx); perovskite solar cells; p-i-n perovskite solar cells; surface treatments

资金

  1. National Research Foundation, Prime Ministers Office, Singapore, under the Solar CRP [S18-1176-SCRP]
  2. NRF [2018-ITC001-001]

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The performance of perovskite solar cells is largely determined by the composition of perovskite and the selection of electron and hole transport layers. Surface modifications on NiOx films can improve the interface quality between NiOx films and perovskite active layers, leading to higher photovoltaic performance.
The performances of perovskite solar cells (PSCs) largely depend on the perovskite compositions and the selection of electron and hole transport layers (ETLs and HTLs). The p-type NiOx films are largely used as HTLs in p-i-n PSCs, thanks to their high transparency, processing versatility, cost-effectiveness, and easy integration within tandem devices. Several studies have shown that surface modifications on NiOx films remove the surface defects, increase the NiOx conductivity, and alter the band offset, consequently improving the interfaces between NiOx films and the perovskite active layer. Indeed, besides improving the NiOx intrinsic properties, the surface treatments also lead, in many cases, to superior perovskite quality driving high photovoltaic performance.

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