4.8 Review

Prospects of Electrode Materials and Electrolytes for Practical Potassium-Based Batteries

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Summary: The research successfully assembled an all-organic aqueous potassium dual-ion full battery with high safety, reversible capacity, long cycle stability, and high coulombic efficiency.

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Summary: A novel vacuum-assisted strategy is proposed to form CoSe2 nanocrystals encapsulated within N-doped carbon matrices in hollow mesoporous carbon nanospheres (CoSe2@NC/HMCS). The resulting composite, CoSe2@NC/HMCS, exhibits excellent cycling stability and rate capability as an anode material for potassium-ion batteries (KIBs). The dual confinement system of N-doped carbon matrix and small-sized pores effectively prevents overgrowth of CoSe2 nanocrystals, contributing to the outstanding electrochemical performance of the composite.

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Blowing Iron Chalcogenides into Two-Dimensional Flaky Hybrids with Superior Cyclability and Rate Capability for Potassium-Ion Batteries

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Manipulating the Solvation Structure of Nonflammable Electrolyte and Interface to Enable Unprecedented Stability of Graphite Anodes beyond 2 Years for Safe Potassium-Ion Batteries

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Summary: This study presents a nonflammable, moderate-concentration electrolyte highly compatible with graphite anodes that exhibits exceptional cycling stability. The stability of the electrolyte is attributed to the nearly 100% solvation of TMP molecules with K+ cations and the formation of a F-rich solid electrolyte interphase. The findings highlight the importance of electrolyte-interface compatibility and offer new opportunities for designing safe and practical PIBs.

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Electrolyte-Mediated Stabilization of High-Capacity Micro-Sized Antimony Anodes for Potassium-Ion Batteries

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Summary: Alloying anodes have high capacity in potassium-ion batteries, but their capacity fading has limited practical applications. This study demonstrates that an antimony alloy anode can be stabilized by electrolyte engineering, delivering high and stable capacities without the need for nanostructural engineering or carbon modification. By tuning the K+ solvation structure through electrolyte composition, the study presents a new guideline for stabilizing metal-ion batteries using alloying anodes.

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Summary: With increasing demand for grid-scale energy storage, potassium-ion batteries (PIBs) have emerged as promising complements or alternatives to commercial lithium-ion batteries. However, the low energy density and unstable cycle life of cathode materials are current challenges that need to be addressed in the development of next-generation PIBs.

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Magnetic Field Assisted Construction of Hollow Red P Nanospheres Confined in Hierarchical N-Doped Carbon Nanosheets/Nanotubes 3D Framework for Efficient Potassium Storage

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Summary: The study demonstrates that black phosphorus nanosheets (BPNSs) with an ultrathin metal-organic-framework (MOF) interphase layer exhibit regulated potassium storage behavior for high-performance potassium-ion capacitors (KICs). The protective MOF interphase layer with ordered pores and high chemical/mechanical stability facilitates K ion diffusion and accommodates electrode volume change, leading to improved reaction kinetics and enhanced cycle stability. The BPNS@MOF electrode as KIC anodes demonstrates outstanding cycle performance exceeding that of most current KICs.

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Cost-effective hard-soft carbon composite anodes with promising potassium ions storage performance

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Potassium-ion battery cathodes: Past, present, and prospects

Zhenrui Wu et al.

Summary: Potassium-ion batteries (KIBs) have demonstrated high energy densities and power densities since 2004, with Prussian blue analogs (PBAs) currently being the most suitable cathodes. Other cathodes, such as tunnel-type manganese oxide and bilayered vanadium pentoxide, also exhibit stable energy densities over 500 Wh kg(-1). However, developing competitive high energy density KIB cathodes with stable and long cycling life remains a challenge.

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Zhanheng Yan et al.

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Summary: This study successfully synthesized superior heterostructure anode material using a chemical vapor deposition method, demonstrating excellent rate performance and high reversible capacity. Through strong interfacial interactions, it achieved easy K+ diffusion, enhanced overall conductivity, boosted high-power performance, and reinforced structural stability of the electrodes.

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Phase Engineering of Nickel Sulfides to Boost Sodium- and Potassium-Ion Storage Performance

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