期刊
MATERIALS TODAY COMMUNICATIONS
卷 29, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.mtcomm.2021.102878
关键词
Energetic polymer; Mannich reaction; Benzoxazine
In this study, three new energetic benzoxazine monomers were synthesized via a one-step Mannich reaction process with explosive nitro groups incorporated in different positions. The synthesized monomers were characterized by various techniques and their thermomechanical properties and thermal stability were evaluated. The para position was found to provide the highest calorific value and the monomer ignited at 267 degrees Celsius.
In this study, three new energetic benzoxazine monomers were synthesized via a one-step Mannich reaction process involving the incorporation of explosophore nitro groups (NO2) in different positions (ortho, meta and para) into the monomer backbone. The molecular structures of the synthesized monomers were confirmed by FTIR, H-1 and (CNMR)-C-13 techniques. The curing behavior, thermomechanical properties and the thermal stability were assessed by DSC-TGA analyses. All monomers displayed two exothermic peaks related to the polymerization and degradation steps except 4-NBZ that present the polymerization and the degradation phenomena through one unique exotherm pic. The energetic performances were evaluated by the determination of the heat of combustion using a bomb calorimeter in an oxygen atmosphere. The results indicated that the para position provided the benzoxazine monomers with a high calorific value comparable to that of the nitrocellulose (about 10.401 kJ/g). Meanwhile, the aforementioned monomer was found to ignite at a temperature of about 267 degrees C. Overall, this study showed that the ease of synthesis of the benzoxazine resins via Mannich reaction can be further extended the energetic field and further researches are undergoing to fully unravel the potential of these exceptional materials.
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