期刊
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS
卷 46, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.colcom.2021.100575
关键词
Hybrid materials; Conductive polymers; Graphene oxide; Ultrathin films; Polydiacetylene; Photovoltaics
资金
- Russian Science Foundation [20-1300279]
A new method for interfacial self-assembly of graphene oxide (GO) and 10,12-pentacosadiynoic acid into nanometer-thick light-absorbing films exhibiting synergetic enhancement of conductive properties is developed.
A new method for interfacial self-assembly of graphene oxide (GO) and 10,12-pentacosadiynoic acid into nanometer-thick light-absorbing films exhibiting synergetic enhancement of conductive properties is developed. The blue form of polydiacetylene (PDA) nanopatches with a thickness of 5-10 nm is stabilized through the interactions between GO and PDA. The hole-transferring polymer decreases contact resistance in the GO sublayer through healing the gaps between the GO nanosheets. The separation of electron-hole pairs at the PDA/GO interface under applied electric field leads to a doping-free enhancement of the in-plane surface conductivity by 6 orders of magnitude up to 46.4 S.cm(-1) with respect to those of individual components. These PDA/GO nano-composites were applied as ultrathin diodes/photodiodes in a solar cell by creating a PDA/C-60 heterojunction and a light-induced cross-layer charge transfer. The method can be adapted to a variety of polymerizable light-absorbing surfactants for fabricating GO-based nanohybrids for photoelectronics.
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