期刊
ACS OMEGA
卷 6, 期 39, 页码 25151-25161出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.1c02481
关键词
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资金
- State Key Basic Research Program of the PRC [2018YFC0310900]
- National Natural Science Foundation of China [21871018, 21732001, 21672017]
- Guangdong Science and Technology Program [2017B030314002]
- Shenzhen Science and Technology Program [KQTD20190929174023858]
- Shenzhen Science and Technology Innovation Committee [GXWD20201231165807007-20200812100115001, JCYJ20180504165454447]
- Industry and Information Technology Bureau of Shenzhen Municipality [201806151622209330]
- National Ten Thousand Talent Program (the Leading Talent Tier)
A palladium-catalyzed ortho C-H arylation reaction with MHP as the directing group has been investigated, generating biaryl derivatives in an environmentally friendly manner and tolerating a wide range of functional groups. The directing group in the product can be easily removed under mild reductive conditions.
Palladium-catalyzed C(sp(2))-H arylation of ortho C-H bonds involving 2-(1-methylhydrazinyl)pyridine (MHP) as the directing group has been investigated. The reaction proceeds smoothly under an air atmosphere to generate biaryl derivatives in an environmentally friendly manner while tolerating a wide range of functional groups. Notably, the directing group present in the product could be easily removed under mild reductive conditions.
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