4.6 Article

Experimental and Simulation Studies on Nonwoven Polypropylene- Nitrile Rubber Blend: Recycling of Medical Face Masks to an Engineering Product

期刊

ACS OMEGA
卷 -, 期 -, 页码 -

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.1c04913

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资金

  1. government of Kerala through the Kerala State Higher Education Council (KSHEC)
  2. Kerala State Council for Science, Technology and Environment (KSCSTE)
  3. National Science Foundation through the ND EPSCoR award [IIA-1355466]
  4. State of North Dakota
  5. NSF MRI Award [2019077]
  6. Extreme Science and Engineering Discovery Environment (XSEDE) [TGDMR110088]
  7. Office of Advanced Cyberinfrastructure (OAC)
  8. Direct For Computer & Info Scie & Enginr [2019077] Funding Source: National Science Foundation

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A novel method for recycling medical face masks has been studied, which involves incorporating nonwoven polypropylene fiber and acrylonitrile butadiene rubber to produce a high percentage economy PP-NBR blend. Experimental and simulation studies demonstrate the excellent thermomechanical properties of the blend.
The battle against the COVID-19 pandemic counters the waste management system, as billions of single-use face masks are used per day all over the world. Proper disposal of used face masks without jeopardizing the health and the environment is a challenge. Herein, a novel method for recycling of medical face masks has been studied. This method incorporates the nonwoven polypropylene (PP) fiber, which is taken off from the mask after disinfecting it, with acrylonitrile butadiene rubber (NBR) using maleic anhydride as the compatibilizer, which results in a PP-NBR blend with a high percentage economy. The PP-NBR blends show enhanced thermomechanical properties among which, 70 wt % PP content shows superior properties compared to other composites with 40, 50, and 60 wt % of PP. The fully Atomistic simulation of PP-NBR blend with compatibilizer shows an improved tensile and barrier properties, which is in good agreement with the experimental studies. The molecular dynamics simulation confirms that the compatibility between non-polar PP and polar NBR phases are vitally important for increasing the interfacial adhesion and impeding the phase separation.

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