期刊
INTERNATIONAL JOURNAL OF GREEN ENERGY
卷 14, 期 2, 页码 113-120出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/15435075.2016.1233495
关键词
Anticorrosion coating; electroactive polymer; superhydrophobic
资金
- National Science council of Republic of China [MOST-104-2113-M-033-001-MY3, MOST-103-2221-E-167 -037 -MY3]
A novel superhydrophobicelectroactive fluorinated polyimide (HEFPI) was first synthesized from aniline trimer and 4,4-(Hexafluoroisopropylidene) diphthalic anhydride. The HEFPI could be fabricated as superhydrophobicfilm by replicated the surface of the Xanthosomasagittifolium leaves. The water contact angle of HEFPI film reaches as high as 157 degrees and the superhydrophobic property of HEFPI could coat on cold-rolled steel (CRS) to prevent the metal corrosion. Electroactivity of EFPI was evaluated by performing electrochemical cyclic voltammetry study. Besides, redox catalytic capabilities of aniline trimer units existed in HEFPI main chain may induce the formation of passive metal oxide layers on the CRS electrode. The synergistic effects (hydrophobic property and passive metal oxide layers) make the HEFPI coating has great potential for advanced anticorrosion material.
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