期刊
BIOMOLECULES
卷 12, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/biom12010028
关键词
chemical ratchet; kinetics; reaction theory; rate equation; transition-state theory; detailed balance; thermal equilibrium
When a reaction is accompanied by a change that occurs at a speed close to or slower than the reaction rate, a circulating reaction flow can exist in the macroscopic stationary state. If the accompanying change is in equilibrium at the timescale of the relevant reaction, the transition-state theory can eliminate the flow.
When a reaction is accompanied by a change with the speed close to or slower than the reaction rate, a circulating reaction flow can exist among the reaction states in the macroscopic stationary state. If the accompanying change were at equilibrium in the timescale of the relevant reaction, the transition-state theory would hold to eliminate the flow.
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