期刊
FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY
卷 9, 期 -, 页码 -出版社
FRONTIERS MEDIA SA
DOI: 10.3389/fbioe.2021.815953
关键词
green corrosion inhibitor; electrochemical impedance spectra; potentiodynamic polarization; weight loss method; anti-corrosion mechanism
资金
- National Natural Science Foundation of China [51971067, 52001080]
- China Postdoctoral Science Foundation [2020M682650]
- Platform Research Capability Enhancement Project of Guangzhou University [69-620939]
- Guangzhou University's 2020 Training Program for Talent [69-62091109]
- Science and Technology Research Project of Guangzhou [202102020467]
The parsley extract (PLE) was used as a corrosion inhibitor in combination with iodide, exhibiting an optimal corrosion inhibition efficiency of 99%. The combined inhibitor showed a favorable long-term corrosion inhibition effect, with over 90% inhibition efficiency maintained after 144 hours. The introduction of iodide led to a higher negative charge amount on the carbon steel surface, facilitating the interaction between the corrosion inhibitor and Fe atoms.
The parsley extract (PLE) was prepared using absolute ethyl alcohol. The PLE and synergistic iodide were firstly utilized as efficacious corrosion inhibitors to slow down the corrosion rate of carbon steel-Q235 in 0.5 mol/L H2SO4 solution. The anti-corrosion performance was researched by weight loss method, electrochemical tests, surface analysis and quantum chemistry calculation. Results of electrochemical and weight loss tests show that the synergetic PLE and I- exhibit the optimal corrosion inhibition efficiency 99%. The combined inhibitor displays the favorable long-term corrosion inhibition effect, and the inhibition efficiency can maintain more than 90% after 144 h immersion. The introduction of I- makes carbon steel surface with higher negative charge amount, which could be beneficial to the interaction between corrosion inhibitor and Fe atoms. The adsorption behavior obeys the Langmuir isotherm adsorption, and involves chemical and physical adsorption. On the basis of electrochemical consequences and theoretical calculation, the adsorption process and anti-corrosion mechanisms are further explored.
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