期刊
MOLECULAR CATALYSIS
卷 518, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.mcat.2021.112093
关键词
ZIF-67; Palladium; Cobalt; Copper; Sonogashira; Reduction reaction
资金
- Institute for Advanced Studies in Basic Sciences (IASBS) Research Council
- Iran National Science Founda-tion (INSF) [4003055]
- Spanish Ministerio de Econo-mia y Competitividad (MINECO) [CTQ2013-43446-P, CTQ2014-51912-REDC]
- Spanish Ministerio de Economia, Industria y Competitividad, Agencia Estatal de Investigacion (AEI)
- Fondo Europeo de Desarrollo Regional (FEDER, EU) [CTQ2016-76782-P, CTQ2016-80375-P, CTQ2017-82935-P, PID2019-107268GB-I00]
- Generalitat Valenciana [IDIFEDER/2021/013]
- University of Alicante
A bimetallic PdCu catalyst supported on amine functionalized ZIF-67 has been found to exhibit high activity and stability in Sonogashira-Hagihara coupling reaction and 4-nitrophenol reduction reaction. It shows superior efficiency compared to other reported catalysts in the same transformations.
A bimetallic PdCu supported on amine functionalized ZIF-67 is shown to be efficient catalyst in SonogashiraHagihara coupling reaction of aryl iodides at room temperature and aryl bromides at 40 oC. In addition, the catalyst is used in the reduction of 4-nitrophenol (4-NP) at room temperature. The analyses of several experiments are developed in order to demonstrate the existence of synergetic affects between Pd, Cu and Co particles in the named reactions. The stability and reusability of this catalyst are also assessed and its efficiency is compared with other reported catalysts in the same transformations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
